Home / Publications / Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides

Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides

Inga Mikhailovna Aladzheva 1
Inga Mikhailovna Aladzheva
, 
Olga Vladimirovna Bykhovskaya 1
Olga Vladimirovna Bykhovskaya
, 
Dmitrii Ivanovich Lobanov 1
Dmitrii Ivanovich Lobanov
, 
Konstantin Alexandrovich Lyssenko 1
Konstantin Alexandrovich Lyssenko
, 
Oleg Valer'ievich Shishkin 2
Oleg Valer'ievich Shishkin
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
, 
Tatyana Alekseevna Mastryukova 1
Tatyana Alekseevna Mastryukova
2 STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
10.1070/MC1996v006n02ABEH000574
Published 1996-04-30
Communication , Volume 6, Issue 2, 48-50
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Aladzheva I. M. et al. Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 48-50.
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Aladzheva I. M., Bykhovskaya O. V., Lobanov D. I., Lyssenko K. A., Shishkin O. V., Antipin M. Y., Struchkov Y. T., Mastryukova T. A. Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 48-50.
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TY - JOUR
DO - 10.1070/MC1996v006n02ABEH000574
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000574
TI - Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides
T2 - Mendeleev Communications
AU - Aladzheva, Inga Mikhailovna
AU - Bykhovskaya, Olga Vladimirovna
AU - Lobanov, Dmitrii Ivanovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Shishkin, Oleg Valer'ievich
AU - Antipin, Mikhail Yuvenal'evich
AU - Struchkov, Yuri Timofeevich
AU - Mastryukova, Tatyana Alekseevna
PY - 1996
DA - 1996/04/30
PB - Mendeleev Communications
SP - 48-50
IS - 2
VL - 6
ER -
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@article{1996_Aladzheva,
author = {Inga Mikhailovna Aladzheva and Olga Vladimirovna Bykhovskaya and Dmitrii Ivanovich Lobanov and Konstantin Alexandrovich Lyssenko and Oleg Valer'ievich Shishkin and Mikhail Yuvenal'evich Antipin and Yuri Timofeevich Struchkov and Tatyana Alekseevna Mastryukova},
title = {Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000574},
number = {2},
pages = {48--50},
doi = {10.1070/MC1996v006n02ABEH000574}
}
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Aladzheva, Inga Mikhailovna, et al. “Intramolecular alkylation of 3- and 4-halogenoalkyldiphenylphosphine sulfides. Ring-chain halogenotropic tautomerism of 2,2-diphenyl-l,2λ4-thiaphospholanium and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodides.” Mendeleev Communications, vol. 6, no. 2, Apr. 1996, pp. 48-50. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000574.

Abstract

Heating of 3- and 4-chloroalkyldiphenylphosphine sulfides la,b with sodium iodide in acetone leads to 2,2-diphenyl-l,2λ4-thiaphospholanium iodide 2a and 2,2-diphenyl-l,2λ4-thiaphosphorinanium iodide 2b; relatively uncommon ring-chain halogenotropic tautomerism is observed in solutions of these compounds.

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