Home / Publications / Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups

Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups

Shamil Nizamov 1
Shamil Nizamov
Andrzej Kwast 1
Andrzej Kwast
Published 1996-04-30
CommunicationVolume 6, Issue 2, 43-44
10
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Makosza M., Nizamov S., Kwast A. Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 43-44.
GOST all authors (up to 50) Copy
Makosza M., Nizamov S., Kwast A. Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 43-44.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1996v006n02ABEH000570
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000570
TI - Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups
T2 - Mendeleev Communications
AU - Makosza, Mieczyslaw
AU - Nizamov, Shamil
AU - Kwast, Andrzej
PY - 1996
DA - 1996/04/30
PB - Mendeleev Communications
SP - 43-44
IS - 2
VL - 6
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1996_Makosza,
author = {Mieczyslaw Makosza and Shamil Nizamov and Andrzej Kwast},
title = {Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000570},
number = {2},
pages = {43--44},
doi = {10.1070/MC1996v006n02ABEH000570}
}
MLA
Cite this
MLA Copy
Makosza, Mieczyslaw, et al. “Vicarious nucleophilic substitution of hydrogen in electrophilic aldimines: synthesis of enamines substituted with electron-withdrawing groups.” Mendeleev Communications, vol. 6, no. 2, Apr. 1996, pp. 43-44. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000570.

Abstract

Strongly electrophilic benzaldimines react with α -chlorocarbanions giving two types of substituted enamines, via vicarious nucleophilic substitution of hydrogen or a cyclisation-ring opening process.

References

1.
Vicarious nucleophilic substitution of hydrogen
Makosza M., Winiarski J.
Accounts of Chemical Research, 1987
2.
Nucleophilic substitution of hydrogen in electrophilic alkenes
Mąkosza M., Kwast A.
Journal of the Chemical Society Chemical Communications, 1984
4.
Addition of .alpha.-metalated chloromethanesulfonamides to unsaturated linkages
Christensen L.W., Seaman J.M., Truce W.E.
Journal of Organic Chemistry, 1973
5.
Carbonyl-Stabilized Sulfonium Ylids. Reaction with Schiff Bases
Speziale A.J., Tung C.C., Ratts K.W., Yao A.
Journal of the American Chemical Society, 1965
6.
Preparation ofN-Tosylaldimines
Love B.E., Raje P.S., Williams II T.C.
Synlett, 1994
10.
Asymmetric Synthesis and Reactions of cis-N-(p-Toluenesulfinyl)aziridine-2-carboxylic Acids