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Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study

Viktor Adol'fovich Benderskii 1
Viktor Adol'fovich Benderskii
, 
Albert Udovich Goldschleger 1
Albert Udovich Goldschleger
, 
Alexander Vladimirovich Akimov 1
Alexander Vladimirovich Akimov
, 
Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
, 
Charles A Wight 2
Charles A Wight
10.1070/MC1995v005n06ABEH000549
Published 1995-12-31
Communication , Volume 5, Issue 6, 245-247
3
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Benderskii V. A. et al. Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 245-247.
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Benderskii V. A., Goldschleger A. U., Akimov A. V., Misochko E. Y., Wight C. A. Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 245-247.
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TY - JOUR
DO - 10.1070/MC1995v005n06ABEH000549
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000549
TI - Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study
T2 - Mendeleev Communications
AU - Benderskii, Viktor Adol'fovich
AU - Goldschleger, Albert Udovich
AU - Akimov, Alexander Vladimirovich
AU - Misochko, Evgenii Yakovlevich
AU - Wight, Charles A
PY - 1995
DA - 1995/12/31
PB - Mendeleev Communications
SP - 245-247
IS - 6
VL - 5
ER -
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@article{1995_Benderskii,
author = {Viktor Adol'fovich Benderskii and Albert Udovich Goldschleger and Alexander Vladimirovich Akimov and Evgenii Yakovlevich Misochko and Charles A Wight},
title = {Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000549},
number = {6},
pages = {245--247},
doi = {10.1070/MC1995v005n06ABEH000549}
}
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Benderskii, Viktor Adol'fovich, et al. “Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study.” Mendeleev Communications, vol. 5, no. 6, Dec. 1995, pp. 245-247. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000549.

Abstract

Ultraviolet laser photolysis of dilute mixtures of F2 and C2H4 in solid argon form a 2-fluoroethyl radical by addition of translationally ‘hot’ as well as thermal F atoms to ethene; at T > 20 K the major channel is the thermal reaction, which converts up to 25% of ethene to 2-fluoroethyl radical.

References

1.
Misochko E.Y., Benderskii V.A., Goldschleger A.U., Akimov A.V.
Mendeleev Communications, 1995
7.
10.1070/MC1995v005n06ABEH000549_bib7
Jacox
Chemistry and Physics of Matrix-isolated Species, 1989
8.
Photodissociation of F2 and mobility of F atoms in crystalline argon
Feld J., Kunttu H., Apkarian V.A.
Journal of Chemical Physics, 1990
9.
Reactions of fluorine atoms
Jones W.E., Skolnik E.G.
Chemical Reviews, 1976