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Polyhydrate 1,10-Diaza-18-crown-6·8.25H₂O

Konstantin Anatol'evich Udachin ¹

Konstantin Anatol'evich Udachin

Janusz Lipkowski ²

Janusz Lipkowski

¹ A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

² Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

10.1070/MC1995v005n06ABEH000545

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Published 1995-12-31

Communication , Volume 5, Issue 6, 237-238

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Udachin K. A., Lipkowski J. Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 237-238.

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Udachin K. A., Lipkowski J. Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 237-238.

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TY - JOUR

DO - 10.1070/MC1995v005n06ABEH000545

UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000545

TI - Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O

T2 - Mendeleev Communications

AU - Udachin, Konstantin Anatol'evich

AU - Lipkowski, Janusz

PY - 1995

DA - 1995/12/31

PB - Mendeleev Communications

SP - 237-238

IS - 6

VL - 5

ER -

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@article{1995_Udachin,

author = {Konstantin Anatol'evich Udachin and Janusz Lipkowski},

title = {Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O},

journal = {Mendeleev Communications},

year = {1995},

volume = {5},

publisher = {Mendeleev Communications},

month = {Dec},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000545},

number = {6},

pages = {237--238},

doi = {10.1070/MC1995v005n06ABEH000545}

}

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Udachin, Konstantin Anatol'evich, and Janusz Lipkowski. “Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O.” Mendeleev Communications, vol. 5, no. 6, Dec. 1995, pp. 237-238. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000545.

Abstract

The phase diagram of the system 1,10-diaza-18-crown-6–H₂O has been studied; polyhydrate 1,10-diaza-18-crown-6-8.25H₂O, which melts incongruently at 16.0 °C, has been found in this system. Each cavity of the three-dimensional framework made of water molecules accommodates four molecules of crown ether; the hydrate has the following crystallographic parameters: a = 18.848(2), c= 13.159(2) Å (T = −100°C), space group P4₂/n and Z = 8.

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