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An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO

Leonid Gennad'evich Menchikov 1
Leonid Gennad'evich Menchikov
, 
Andrey V Vorogushin 2
Andrey V Vorogushin
, 
Olga Semionovna Korneva 1
Olga Semionovna Korneva
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC1995v005n06ABEH000536
Published 1995-12-31
Communication , Volume 5, Issue 6, 223-224
13
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Menchikov L. G. et al. An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 223-224.
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Menchikov L. G., Vorogushin A. V., Korneva O. S., Nefedov O. M. An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 223-224.
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TY - JOUR
DO - 10.1070/MC1995v005n06ABEH000536
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000536
TI - An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO
T2 - Mendeleev Communications
AU - Menchikov, Leonid Gennad'evich
AU - Vorogushin, Andrey V
AU - Korneva, Olga Semionovna
AU - Nefedov, Oleg Matveevich
PY - 1995
DA - 1995/12/31
PB - Mendeleev Communications
SP - 223-224
IS - 6
VL - 5
ER -
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@article{1995_Menchikov,
author = {Leonid Gennad'evich Menchikov and Andrey V Vorogushin and Olga Semionovna Korneva and Oleg Matveevich Nefedov},
title = {An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000536},
number = {6},
pages = {223--224},
doi = {10.1070/MC1995v005n06ABEH000536}
}
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Menchikov, Leonid Gennad'evich, et al. “An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO.” Mendeleev Communications, vol. 5, no. 6, Dec. 1995, pp. 223-224. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000536.

Abstract

Hydrolysis of alkyl halides in the presence of copper and its salts in aqueous DMSO (molar ratio organohalide:CuSO4·5H2O:DMSO:H2O = 1:1:10–20:12–25) at 100–117 °C gives alcohols in high yields. Aryl halides containing no activating substituents are inert under the reaction conditions.

References

1.
10.1070/MC1995v005n06ABEH000536_bib1
Houben-Weyl
Methoden der Organischen Chemie, 1979
2.
10.1070/MC1995v005n06ABEH000536_bib2
Weygand-Hilgetag
Organisch-Chemische Experimentierkunst, 1964
3.
10.1070/MC1995v005n06ABEH000536_bib3
Korneva
Izv. Akad. Nauk SSSR., Ser. Khim., 1991