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Synthesis of π-Complexes of Codeine with Iron and Molybdenum

Valery Nikolaevich Kalinin ¹

Valery Nikolaevich Kalinin

Vladimir Vladimirovich Derunov ¹

Vladimir Vladimirovich Derunov

Leendert Maat ²

Leendert Maat

Jin K Park ³

Jin K Park

Helmut Schmidhammer ⁴

Helmut Schmidhammer

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

² Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Delft, the Netherlands

³ Dong Kook Pharmaceutical Co., Ltd., Seoul, Korea

⁴ Institute of Pharmacy, University of Innsbruck, Innsbruck, Austria

10.1070/MC1995v005n06ABEH000535

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Published 1995-12-31

Communication , Volume 5, Issue 6, 222-223

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Kalinin V. N. et al. Synthesis of π-Complexes of Codeine with Iron and Molybdenum // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 222-223.

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Kalinin V. N., Derunov V. V., Maat L., Park J. K., Schmidhammer H. Synthesis of π-Complexes of Codeine with Iron and Molybdenum // Mendeleev Communications. 1995. Vol. 5. No. 6. pp. 222-223.

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TY - JOUR

DO - 10.1070/MC1995v005n06ABEH000535

UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000535

TI - Synthesis of π-Complexes of Codeine with Iron and Molybdenum

T2 - Mendeleev Communications

AU - Kalinin, Valery Nikolaevich

AU - Derunov, Vladimir Vladimirovich

AU - Maat, Leendert

AU - Park, Jin K

AU - Schmidhammer, Helmut

PY - 1995

DA - 1995/12/31

PB - Mendeleev Communications

SP - 222-223

IS - 6

VL - 5

ER -

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@article{1995_Kalinin,

author = {Valery Nikolaevich Kalinin and Vladimir Vladimirovich Derunov and Leendert Maat and Jin K Park and Helmut Schmidhammer},

title = {Synthesis of π-Complexes of Codeine with Iron and Molybdenum},

journal = {Mendeleev Communications},

year = {1995},

volume = {5},

publisher = {Mendeleev Communications},

month = {Dec},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000535},

number = {6},

pages = {222--223},

doi = {10.1070/MC1995v005n06ABEH000535}

}

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Kalinin, Valery Nikolaevich, et al. “Synthesis of π-Complexes of Codeine with Iron and Molybdenum.” Mendeleev Communications, vol. 5, no. 6, Dec. 1995, pp. 222-223. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n06ABEH000535.

Abstract

Treatment of 6β-chloro-6-deoxycodeine 1 or 8β-bromo-8-deoxypseudocodeine 2 with Fe(CO)₅ or Fe₂(CO)₉ yields 6-demethoxythebaine 3 and the π-diene iron complex 4; compound 1 or 2 reacts with Mo(CO)₆ to give the π-allylic molybdenum complexes 5 and 6, respectively.