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An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl

Naum Markovich Gontmakher 1
Naum Markovich Gontmakher
, 
Olga Igorevna Barteneva 1
Olga Igorevna Barteneva
, 
Igor Victorovich Dorogan 1
Igor Victorovich Dorogan
, 
Ruslan Mikhailovich Minyaev 1
Ruslan Mikhailovich Minyaev
10.1070/MC1995v005n05ABEH000529
Published 1995-10-30
Communication , Volume 5, Issue 5, 207-208
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Gontmakher N. M. et al. An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 207-208.
GOST all authors (up to 50) Copy
Gontmakher N. M., Barteneva O. I., Dorogan I. V., Minyaev R. M. An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 207-208.
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TY - JOUR
DO - 10.1070/MC1995v005n05ABEH000529
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000529
TI - An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl
T2 - Mendeleev Communications
AU - Gontmakher, Naum Markovich
AU - Barteneva, Olga Igorevna
AU - Dorogan, Igor Victorovich
AU - Minyaev, Ruslan Mikhailovich
PY - 1995
DA - 1995/10/30
PB - Mendeleev Communications
SP - 207-208
IS - 5
VL - 5
ER -
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@article{1995_Gontmakher,
author = {Naum Markovich Gontmakher and Olga Igorevna Barteneva and Igor Victorovich Dorogan and Ruslan Mikhailovich Minyaev},
title = {An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000529},
number = {5},
pages = {207--208},
doi = {10.1070/MC1995v005n05ABEH000529}
}
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Gontmakher, Naum Markovich, et al. “An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl.” Mendeleev Communications, vol. 5, no. 5, Oct. 1995, pp. 207-208. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000529.

Abstract

An anomalous chemical mechanism of aluminium dissolution has been experimentally determined in electrolytes containing HCI based on proton-donor solvents (methanol, ethanol, propanol, water), and this mechanism has been explained by a new theoretical approach based on the comparison of the work function of aluminium with the electron affinity of oxidizing complexes.

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