Home / Publications / Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K

Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K

Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
, 
Viktor Adol'fovich Benderskii 1
Viktor Adol'fovich Benderskii
, 
Albert Udovich Goldschleger 1
Albert Udovich Goldschleger
, 
Alexander Vladimirovich Akimov 1
Alexander Vladimirovich Akimov
10.1070/MC1995v005n05ABEH000524
Published 1995-10-30
Communication , Volume 5, Issue 5, 198-200
10
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Misochko E. Y. et al. Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 198-200.
GOST all authors (up to 50) Copy
Misochko E. Y., Benderskii V. A., Goldschleger A. U., Akimov A. V. Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 198-200.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1995v005n05ABEH000524
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000524
TI - Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K
T2 - Mendeleev Communications
AU - Misochko, Evgenii Yakovlevich
AU - Benderskii, Viktor Adol'fovich
AU - Goldschleger, Albert Udovich
AU - Akimov, Alexander Vladimirovich
PY - 1995
DA - 1995/10/30
PB - Mendeleev Communications
SP - 198-200
IS - 5
VL - 5
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1995_Misochko,
author = {Evgenii Yakovlevich Misochko and Viktor Adol'fovich Benderskii and Albert Udovich Goldschleger and Alexander Vladimirovich Akimov},
title = {Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000524},
number = {5},
pages = {198--200},
doi = {10.1070/MC1995v005n05ABEH000524}
}
MLA
Cite this
MLA Copy
Misochko, Evgenii Yakovlevich, et al. “Reactions of Thermalized Fluorine Atoms with CH4 and CH3, Trapped in an Argon Matrix at 13–20 K.” Mendeleev Communications, vol. 5, no. 5, Oct. 1995, pp. 198-200. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000524.

Abstract

Accumulation and conversion of CH3 radicals upon F2 photolysis in ternary mixtures Ar:F2:CH4 has been studied with EPR spectroscopy; the CH3 radical formation during photolysis period is caused by the reaction of’hot’ F atoms with CH4. At T > 18 K the thermally activated reaction of ’cold’ F atoms with CH4 was also detected; the activation energy of diffusion-controlled recombination of the F atoms falls short of that of F + CH4 reaction.

References

3.
Dynamics of molecular reactions in solids: Photodissociation of F2in crystalline Ar
Alimi R., Gerber R.B., Apkarian V.A.
Journal of Chemical Physics, 1990
4.
Photodissociation of F2 and mobility of F atoms in crystalline argon
Feld J., Kunttu H., Apkarian V.A.
Journal of Chemical Physics, 1990
5.
Misochko E.Y., Benderskii V.A., Goldschleger A.U., Akimov A.V.
Mendeleev Communications, 1994
6.
Theory of Linewidths in Electron Spin Resonance Spectra
Freed J.H., Fraenkel G.K.
Journal of Chemical Physics, 1963
7.
Theory of Line Widths in Electron Spin Resonance Spectra: Motion of Methyl Groups
Freed J.H., Fraenkel G.K.
Journal of the American Chemical Society, 1964
8.
Reactions of fluorine atoms
Jones W.E., Skolnik E.G.
Chemical Reviews, 1976