Home / Publications / Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride

Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride

Leonid Ivanovich Zakharkin 1
Leonid Ivanovich Zakharkin
, 
Valentina Antonovna Ol'shevskaya 1
Valentina Antonovna Ol'shevskaya
, 
Aleksandr Pavlovich Pisarevsky 1
Aleksandr Pavlovich Pisarevsky
, 
Aleksandr Il'ich Yanovsky 1
Aleksandr Il'ich Yanovsky
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
10.1070/MC1995v005n05ABEH000518
Published 1995-10-30
Communication , Volume 5, Issue 5, 190-191
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Zakharkin L. I. et al. Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 190-191.
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Zakharkin L. I., Ol'shevskaya V. A., Pisarevsky A. P., Yanovsky A. I., Struchkov Y. T. Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 190-191.
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TY - JOUR
DO - 10.1070/MC1995v005n05ABEH000518
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000518
TI - Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride
T2 - Mendeleev Communications
AU - Zakharkin, Leonid Ivanovich
AU - Ol'shevskaya, Valentina Antonovna
AU - Pisarevsky, Aleksandr Pavlovich
AU - Yanovsky, Aleksandr Il'ich
AU - Struchkov, Yuri Timofeevich
PY - 1995
DA - 1995/10/30
PB - Mendeleev Communications
SP - 190-191
IS - 5
VL - 5
ER -
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@article{1995_Zakharkin,
author = {Leonid Ivanovich Zakharkin and Valentina Antonovna Ol'shevskaya and Aleksandr Pavlovich Pisarevsky and Aleksandr Il'ich Yanovsky and Yuri Timofeevich Struchkov},
title = {Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000518},
number = {5},
pages = {190--191},
doi = {10.1070/MC1995v005n05ABEH000518}
}
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Zakharkin, Leonid Ivanovich, et al. “Rhodium Complexes of 3-lsocyano-1,2-dicarba-closo-dodecaborane(12): Crystal and Molecular Structure of (η5-Pentamethylcyclopentadienyl)-1,2-dimethyl-3-isocyano-1,2-dicarba-closo-dodecaboran(12)ylrhodium(III) Dichloride.” Mendeleev Communications, vol. 5, no. 5, Oct. 1995, pp. 190-191. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000518.

Abstract

Monomeric isocyano complexes of rhodium(III) have been prepared from 1,2-dimethyl-3-isocyano- 2b and 3-isocyano-1,2-dicarba-closo-dodecaborane(12) 2a and rhodium dimer [(η5-C5Me5)RhCl2]2 1; the structure of the resulting carborane rhodium complex was determined by an X-ray diffraction study.

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