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The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species

Ulrich Koelle 1
Ulrich Koelle
, 
Alexander Dmitrievich Ryabov 2
Alexander Dmitrievich Ryabov
1 Institute of Inorganic Chemistry, Technical University of Aachen
10.1070/MC1995v005n05ABEH000517
Published 1995-10-30
Communication , Volume 5, Issue 5, 187-189
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Koelle U., Ryabov A. D. The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 187-189.
GOST all authors (up to 50) Copy
Koelle U., Ryabov A. D. The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 187-189.
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TY - JOUR
DO - 10.1070/MC1995v005n05ABEH000517
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000517
TI - The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species
T2 - Mendeleev Communications
AU - Koelle, Ulrich
AU - Ryabov, Alexander Dmitrievich
PY - 1995
DA - 1995/10/30
PB - Mendeleev Communications
SP - 187-189
IS - 5
VL - 5
ER -
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@article{1995_Koelle,
author = {Ulrich Koelle and Alexander Dmitrievich Ryabov},
title = {The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000517},
number = {5},
pages = {187--189},
doi = {10.1070/MC1995v005n05ABEH000517}
}
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Koelle, Ulrich, and Alexander Dmitrievich Ryabov. “The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species.” Mendeleev Communications, vol. 5, no. 5, Oct. 1995, pp. 187-189. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000517.

Abstract

A cyclic voltammetry study of the η5-pentamethylcyclopentadienylrhodium (Cp*Rh) complexes [(Cp*Rh)2(μ.-Cl)3]+ and [Cp*RhIIIaq]2+ at pH 6.05 in the absence and in the presence of nicotinamide cofactors indicates that the chloro complex is more advantageous for electrochemical reduction of NAD+ into NADH; the reverse oxidation of NADH by [(Cp*Rh)2(μ-CI)3]+ is insufficiently selective for practical applications according to the 1H NMR data.

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