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Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex

Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
, 
Galina Dmitrievna Gamalevich 1
Galina Dmitrievna Gamalevich
, 
Alexander V Strakhov 2
Alexander V Strakhov
, 
Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
10.1070/MC1995v005n05ABEH000509
Published 1995-10-30
Communication , Volume 5, Issue 5, 175-176
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Serebryakov E. P. et al. Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 175-176.
GOST all authors (up to 50) Copy
Serebryakov E. P., Gamalevich G. D., Strakhov A. V., Vasil'ev A. A. Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex // Mendeleev Communications. 1995. Vol. 5. No. 5. pp. 175-176.
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TY - JOUR
DO - 10.1070/MC1995v005n05ABEH000509
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000509
TI - Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex
T2 - Mendeleev Communications
AU - Serebryakov, Edward Prokof'evich
AU - Gamalevich, Galina Dmitrievna
AU - Strakhov, Alexander V
AU - Vasil'ev, Andrei Alexandrovich
PY - 1995
DA - 1995/10/30
PB - Mendeleev Communications
SP - 175-176
IS - 5
VL - 5
ER -
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@article{1995_Serebryakov,
author = {Edward Prokof'evich Serebryakov and Galina Dmitrievna Gamalevich and Alexander V Strakhov and Andrei Alexandrovich Vasil'ev},
title = {Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000509},
number = {5},
pages = {175--176},
doi = {10.1070/MC1995v005n05ABEH000509}
}
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Serebryakov, Edward Prokof'evich, et al. “Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η6-Arene(tricarbonyl)chromium Complex.” Mendeleev Communications, vol. 5, no. 5, Oct. 1995, pp. 175-176. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n05ABEH000509.

Abstract

Temporary introduction of the Cr(CO)3 ‘ligand’ into the title substrate brings about a manifold increase in the enantioselectivity of its PPL-catalysed hydrolysis (characterised by the enantiomeric ratio parameter, E), and reverses the stereochemical result of the reaction.

References

1.
10.1070/MC1995v005n05ABEH000509_bib1
Gamalevich
Izv. Akad. Nauk, Ser. Khim., 1995
2.
Quantitative analyses of biochemical kinetic resolutions of enantiomers
Chen C.S., Fujimoto Y., Girdaukas G., Sih C.J.
Journal of the American Chemical Society, 1982
4.
10.1070/MC1995v005n05ABEH000509_bib4_1
Yamazaki
Agric. Biol. Chem., 1990
6.
(η6 -Arene)Tricarbonylchromium Complexes
Mahaffy C.A., Pauson P.L., Rausch M.D., Lee W.
Inorganic Syntheses, 1979