Home / Publications / Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile

Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile

Gennadii D Titskii 1
Gennadii D Titskii
, 
Mariya K Turovskaya 1
Mariya K Turovskaya
, 
Aleksandr A Yakovets 1
Aleksandr A Yakovets
1 L.M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine
10.1070/MC1995v005n04ABEH000507
Published 1995-08-31
Communication , Volume 5, Issue 4, 161-162
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Titskii G. D., Turovskaya M. K., Yakovets A. A. Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 161-162.
GOST all authors (up to 50) Copy
Titskii G. D., Turovskaya M. K., Yakovets A. A. Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 161-162.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1995v005n04ABEH000507
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000507
TI - Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile
T2 - Mendeleev Communications
AU - Titskii, Gennadii D
AU - Turovskaya, Mariya K
AU - Yakovets, Aleksandr A
PY - 1995
DA - 1995/08/31
PB - Mendeleev Communications
SP - 161-162
IS - 4
VL - 5
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1995_Titskii,
author = {Gennadii D Titskii and Mariya K Turovskaya and Aleksandr A Yakovets},
title = {Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000507},
number = {4},
pages = {161--162},
doi = {10.1070/MC1995v005n04ABEH000507}
}
MLA
Cite this
MLA Copy
Titskii, Gennadii D., et al. “Kinetics and Mechanism of the Reaction of Benzoyi Chloride with 4-(4’-N,N-Dimethylaminostyryl)pyridine N-Oxide in Acetonitrile.” Mendeleev Communications, vol. 5, no. 4, Aug. 1995, pp. 161-162. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000507.

Abstract

The rate and equilibrium constants for the individual steps in the reaction of benzoyi chloride with 4-(4’-N,N-dimethylamino-styryl)pyridine N-oxide in acetonitrile to afford 1-benzoyloxy-4-(4’-N,N-dimethylaminostyryl)pyridinium chloride have been determined; the slow step of the reaction involves decomposition of a tetrahedral intermediate.

References

1.
10.1070/MC1995v005n04ABEH000507_bib1
Litvinenko
Dokl. Akad. Nauk SSSR, 1967
2.
10.1070/MC1995v005n04ABEH000507_bib2
Titskii
Zh. Org. Khim., 1992
3.
10.1070/MC1995v005n04ABEH000507_bib3
Berezin
Prakticheskii kurs khimicheskoi I fermentativnoi kinetiki, 1976