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Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom

Viktor Mikhailovich Mamaev 1
Viktor Mikhailovich Mamaev
,  , 
Sergei Yakovlevich Ishchenko 1
Sergei Yakovlevich Ishchenko
, 
Vahan Vladimirovich Simonyan 1
Vahan Vladimirovich Simonyan
, 
Eugene Mikhailovich Myshakin 1
Eugene Mikhailovich Myshakin
, 
Andrei Viktorovich Prisyajnuk 2
Andrei Viktorovich Prisyajnuk
, 
Yuri Aleksandrovich Ustynyuk 1
Yuri Aleksandrovich Ustynyuk
10.1070/MC1995v005n04ABEH000494
Published 1995-08-31
Communication , Volume 5, Issue 4, 137-138
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Mamaev V. M. et al. Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 137-138.
GOST all authors (up to 50) Copy
Mamaev V. M., Gloriozov I. P., Ishchenko S. Y., Simonyan V. V., Myshakin E. M., Prisyajnuk A. V., Ustynyuk Y. A. Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 137-138.
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TY - JOUR
DO - 10.1070/MC1995v005n04ABEH000494
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000494
TI - Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom
T2 - Mendeleev Communications
AU - Mamaev, Viktor Mikhailovich
AU - Gloriozov, Igor Pavlovich
AU - Ishchenko, Sergei Yakovlevich
AU - Simonyan, Vahan Vladimirovich
AU - Myshakin, Eugene Mikhailovich
AU - Prisyajnuk, Andrei Viktorovich
AU - Ustynyuk, Yuri Aleksandrovich
PY - 1995
DA - 1995/08/31
PB - Mendeleev Communications
SP - 137-138
IS - 4
VL - 5
ER -
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@article{1995_Mamaev,
author = {Viktor Mikhailovich Mamaev and Igor Pavlovich Gloriozov and Sergei Yakovlevich Ishchenko and Vahan Vladimirovich Simonyan and Eugene Mikhailovich Myshakin and Andrei Viktorovich Prisyajnuk and Yuri Aleksandrovich Ustynyuk},
title = {Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000494},
number = {4},
pages = {137--138},
doi = {10.1070/MC1995v005n04ABEH000494}
}
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Mamaev, Viktor Mikhailovich, et al. “Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom.” Mendeleev Communications, vol. 5, no. 4, Aug. 1995, pp. 137-138. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000494.

Abstract

Quantum rate constant evaluations and kinetic isotope effects for the oxidative addition of CH4 (and CD4) to a bare Pd atom, calculated in terms of the Reaction Path Hamiltonian approximation, show quantum tunneling to play a very important role in the process when T < 200 K.

References

2.
Organometallic chemistry in the gas phase
Eller K., Schwarz H.
Chemical Reviews, 1991
3.
10.1070/MC1995v005n04ABEH000494_bib3
Shilov
The Activation of Saturated Hydrocarbons by Transition Metal Complexes, 1984
5.
IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect
Schultz R.H., Bengali A.A., Tauber M.J., Weiller B.H., Wasserman E.P., Kyle K.R., Moore C.B., Bergman R.G.
Journal of the American Chemical Society, 1994
6.
10.1070/MC1995v005n04ABEH000494_bib6
Activation and Functionalization of Alkanes, 1989
7.
Time-resolved IR spectroscopy in liquid rare gases: direct rate measurement of an intermolecular alkane carbon-hydrogen oxidative addition reaction
Weiller B.H., Wasserman E.P., Bergman R.G., Moore C.B., Pimentel G.C.
Journal of the American Chemical Society, 1989
11.
10.1070/MC1995v005n04ABEH000494_bib11
Bell
The Tunnel Effect in Chemistry, 1980
12.
Reaction-path dynamics for polyatomic systems
Miller W.H.
The Journal of Physical Chemistry, 1983
13.
10.1070/MC1995v005n04ABEH000494_bib13
Rusanov
Zh. Strukt. Khim., 1993
14.
CNDO-S2: a new semiempirical SCF MO method for transition metal organometallics
Filatov M.J., Gritsenko O.V., Zhidomirov G.M.
Journal of Molecular Catalysis, 1989
16.
Theoretical study of the activation of alkane carbon-hydrogen and carbon-carbon bonds by different transition metals
Blomberg M.R., Siegbahn P.E., Nagashima U., Wennerberg J.
Journal of the American Chemical Society, 1991
17.
Incorporation of quantum effects in generalized-transition-state theory
Truhlar D.G., Isaacson A.D., Skodje R.T., Garrett B.C.
The Journal of Physical Chemistry, 1982
18.
10.1070/MC1995v005n04ABEH000494_bib18
Mamaev
Dokl. Akad. Nauk, 1994
19.
10.1070/MC1995v005n04ABEH000494_bib19
Mamaev
Metalloorg. Khim., 1992