Home / Articles / Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate

Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate

Galina Anatol'evna Dushenko 1
Galina Anatol'evna Dushenko
, 
Igor Evguen'evich Mikhailov 1
Igor Evguen'evich Mikhailov
, 
Adolf Zschunke 2
Adolf Zschunke
, 
Nils Hakam 3
Nils Hakam
, 
Clemens Muegge 3
Clemens Muegge
, 
Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
10.1070/MC1995v005n04ABEH000491
Published 31 August 1995 , received 10 March 1995
Communication , Volume 5, Issue 4, 133-134
11
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Dushenko G. A. et al. Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 133-134.
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Dushenko G. A., Mikhailov I. E., Zschunke A., Hakam N., Muegge C., Minkin V. I. Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate // Mendeleev Communications. 1995. Vol. 5. No. 4. pp. 133-134.
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TY - JOUR
DO - 10.1070/MC1995v005n04ABEH000491
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000491
TI - Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate
T2 - Mendeleev Communications
AU - Dushenko, Galina Anatol'evna
AU - Mikhailov, Igor Evguen'evich
AU - Zschunke, Adolf
AU - Hakam, Nils
AU - Muegge, Clemens
AU - Minkin, Vladimir Isaakovich
PY - 1995
DA - 1995/08/31
PB - Mendeleev Communications
SP - 133-134
IS - 4
VL - 5
ER -
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@article{1995_Dushenko,
author = {Galina Anatol'evna Dushenko and Igor Evguen'evich Mikhailov and Adolf Zschunke and Nils Hakam and Clemens Muegge and Vladimir Isaakovich Minkin},
title = {Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000491},
number = {4},
pages = {133--134},
doi = {10.1070/MC1995v005n04ABEH000491}
}
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Dushenko, Galina Anatol'evna, et al. “Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate.” Mendeleev Communications, vol. 5, no. 4, Aug. 1995, pp. 133-134. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n04ABEH000491.
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Abstract

Fast and reversible migrations of the ethoxydithiocarbonate group along the perimeter of the cycloheptatriene ring of 3 have been found to occur through a series of successive 1,7-sigmatropic shifts with an energy barrier in the range 17.4–17.9 kcal mol–1.

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