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The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane

Sergei Vladimirovich Maklakov 1
Sergei Vladimirovich Maklakov
, 
Rafik Grantovich Aivazyan 1
Rafik Grantovich Aivazyan
, 
Vilen Vagarshovich Azatyan 1
Vilen Vagarshovich Azatyan
, 
Pavel Viktorovich Zhirkov 1
Pavel Viktorovich Zhirkov
, 
Lyudmila Fedorovna Satunkina 1
Lyudmila Fedorovna Satunkina
10.1070/MC1995v005n03ABEH000487
Published 1995-06-30
Communication , Volume 5, Issue 3, 120-123
4
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Maklakov S. V. et al. The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 120-123.
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Maklakov S. V., Aivazyan R. G., Azatyan V. V., Zhirkov P. V., Satunkina L. F. The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 120-123.
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TY - JOUR
DO - 10.1070/MC1995v005n03ABEH000487
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000487
TI - The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane
T2 - Mendeleev Communications
AU - Maklakov, Sergei Vladimirovich
AU - Aivazyan, Rafik Grantovich
AU - Azatyan, Vilen Vagarshovich
AU - Zhirkov, Pavel Viktorovich
AU - Satunkina, Lyudmila Fedorovna
PY - 1995
DA - 1995/06/30
PB - Mendeleev Communications
SP - 120-123
IS - 3
VL - 5
ER -
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@article{1995_Maklakov,
author = {Sergei Vladimirovich Maklakov and Rafik Grantovich Aivazyan and Vilen Vagarshovich Azatyan and Pavel Viktorovich Zhirkov and Lyudmila Fedorovna Satunkina},
title = {The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000487},
number = {3},
pages = {120--123},
doi = {10.1070/MC1995v005n03ABEH000487}
}
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Maklakov, Sergei Vladimirovich, et al. “The Critical Transition between Phase Formation Modes in the Pyrolysis of Silane.” Mendeleev Communications, vol. 5, no. 3, Jun. 1995, pp. 120-123. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000487.

Abstract

A jump-wise transition between two different kinetic modes of phase formation in the course of silane pyrolysis has been found experimentally. In one mode the solid phase is formed as an aerosol, in the other as a film; the phenomenon can be reproduced by mathematical analysis of a model mechanism.

References

1.
Silane pyrolysis
Robertson R., Hils D., Gallagher A.
Chemical Physics Letters, 1984
2.
10.1070/MC1995v005n03ABEH000487_bib2
Aivazyan
Fiz. Goren. Vzryv., 1994
3.
Mechanism of the thermally induced gas-phase decomposition of silane: a revisitation
Ring M.A., O'Neal H.E.
The Journal of Physical Chemistry, 1992
4.
Some mechanistic problems in the kinetic modeling of monosilane pyrolysis
Becerra R., Walsh R.
The Journal of Physical Chemistry, 1992
5.
10.1070/MC1995v005n03ABEH000487_bib5
Azatyan
Kinet. Katal., 1993
6.
10.1070/MC1995v005n03ABEH000487_bib6
Azatyan
Kinet. Katal, 1994
7.
10.1070/MC1995v005n03ABEH000487_bib7
Onistchuk
Khim. Fiz., 1992
8.
10.1070/MC1995v005n03ABEH000487_bib8
Onistchuk
Khim. Fiz., 1994
9.
10.1070/MC1995v005n03ABEH000487_bib9
Purnell
Proc. R. Soc. London, 1966
10.
Pyrolysis of monosilane
Ring M.A., Puentes M.J., O'Neal H.E.
Journal of the American Chemical Society, 1970
11.
10.1070/MC1995v005n03ABEH000487_bib11
Krasnoperov
Khim. Fiz., 1988
12.
The decomposition kinetics of disilane and the heat of formation of silylene
Martin J.G., Ring M.A., O'Neal H.E.
International Journal of Chemical Kinetics, 1987
13.
Kinetics of the thermal decomposition of methyldisilane and trisilane
Vanderwielen A.J., Ring M.A., O'Neal H.E.
Journal of the American Chemical Society, 1975
14.
Thermal decomposition kinetics of polysilanes: Disilane, trisilane, and tetrasilane
Martin J.G., O'Neal H.E., Ring M.A.
International Journal of Chemical Kinetics, 1990
15.
Kinetics of Phase Change. I General Theory
Avrami M.
Journal of Chemical Physics, 1939
16.
10.1070/MC1995v005n03ABEH000487_bib16
Kolmogorov
Izv. Akad. Nauk SSSR, Ser. Math., 1937
17.
10.1070/MC1995v005n03ABEH000487_bib17
Frank-Kamenetscii
Mass and Heat Transfer in Chemical Kinetics, 1969