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Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride

Hermann J Frohn 1
Hermann J Frohn
, 
Vadim Victorovich Bardin 2
Vadim Victorovich Bardin
10.1070/MC1995v005n03ABEH000484
Published 1995-06-30
Communication , Volume 5, Issue 3, 114-115
5
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Frohn H. J., Bardin V. V. Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 114-115.
GOST all authors (up to 50) Copy
Frohn H. J., Bardin V. V. Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 114-115.
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TY - JOUR
DO - 10.1070/MC1995v005n03ABEH000484
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000484
TI - Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride
T2 - Mendeleev Communications
AU - Frohn, Hermann J
AU - Bardin, Vadim Victorovich
PY - 1995
DA - 1995/06/30
PB - Mendeleev Communications
SP - 114-115
IS - 3
VL - 5
ER -
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@article{1995_Frohn,
author = {Hermann J Frohn and Vadim Victorovich Bardin},
title = {Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000484},
number = {3},
pages = {114--115},
doi = {10.1070/MC1995v005n03ABEH000484}
}
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Frohn, Hermann J., and Vadim Victorovich Bardin. “Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride.” Mendeleev Communications, vol. 5, no. 3, Jun. 1995, pp. 114-115. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000484.

Abstract

The reactivity of (heptafluoro-1,4-cyclohexadien-1-yl)xenon(ii) hexafluoroarsenate 1 towards a fluoride donor and acceptor has been investigated; the interaction of 1 with NaF led to perfluoro-3-methylenecyclopentene and xenon. No dication [C6F6Xe]2+ was detected by 19F NMR spectroscopy when [1-Xe + -1,4-C6F7] [AsF6]– was treated with SbF5–SO2, SbF5–SO2FCI or neat SbF5.

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