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An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts

Oleg Nikolaevich Chupakhin 1
Oleg Nikolaevich Chupakhin
, 
Boris Victorovich Rudakov 2
Boris Victorovich Rudakov
, 
Padraig McDermott 3
Padraig McDermott
, 
Sergei Gennad'evich Alexeev 2
Sergei Gennad'evich Alexeev
,  , 
Frank Hegarty 3
Frank Hegarty
10.1070/MC1995v005n03ABEH000478
Published 1995-06-30
Communication , Volume 5, Issue 3, 104-105
5
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Chupakhin O. N. et al. An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 104-105.
GOST all authors (up to 50) Copy
Chupakhin O. N., Rudakov B. V., McDermott P., Alexeev S. G., Charushin V. N., Hegarty F. An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts // Mendeleev Communications. 1995. Vol. 5. No. 3. pp. 104-105.
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TY - JOUR
DO - 10.1070/MC1995v005n03ABEH000478
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000478
TI - An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts
T2 - Mendeleev Communications
AU - Chupakhin, Oleg Nikolaevich
AU - Rudakov, Boris Victorovich
AU - McDermott, Padraig
AU - Alexeev, Sergei Gennad'evich
AU - Charushin, Valery Nikolaevich
AU - Hegarty, Frank
PY - 1995
DA - 1995/06/30
PB - Mendeleev Communications
SP - 104-105
IS - 3
VL - 5
ER -
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@article{1995_Chupakhin,
author = {Oleg Nikolaevich Chupakhin and Boris Victorovich Rudakov and Padraig McDermott and Sergei Gennad'evich Alexeev and Valery Nikolaevich Charushin and Frank Hegarty},
title = {An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000478},
number = {3},
pages = {104--105},
doi = {10.1070/MC1995v005n03ABEH000478}
}
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Chupakhin, Oleg Nikolaevich, et al. “An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts.” Mendeleev Communications, vol. 5, no. 3, Jun. 1995, pp. 104-105. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n03ABEH000478.

Abstract

Unusually easy dequaternization has been found to occur on treatment of 1-alkyl-3-morpholino-5-phenyl-1,2,4-triazinium iodides with triethylamine in alcohol or acetone solutions at room temperature; a plausible reaction mechanism has been advanced on the basis of NMR and kinetic studies.

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