Abstract
The amino group of heterocycles has been oxidized to a nitro group using dinitrogen pentoxide; it is suggested that the mechanism of this reaction involves the transformations: amines→ nitramine →nitroso→nitro compound.
References
1.
Churakov A.M., Ioffe S.L., Tartakovskii V.A.
Mendeleev Communications,
1991
2.
Mitschker A., Wedemeyer K.
Synthesis,
1988
3.
Boulton A.J., Kiss M., Saka J.D.
Journal of the Chemical Society Perkin Transactions 1,
1988
4.
10.1070/MC1995v005n03ABEH000477_bib3
Sheremetev
Izv. Akad. Nauk SSSR, Ser. Khim.,
1990
5.
Zawalski R.C., Kovacic P.
Journal of Organic Chemistry,
1979
6.
Novikova T.S., Mel’nikova T.M., Kharitonova O.V., Kulagina V.O., Aleksandrova N.S., Sheremetev A.B., Pivina T.S., Khmel’nitskii L.I., Novikov S.S.
Mendeleev Communications,
1994
7.
10.1070/MC1995v005n03ABEH000477_bib6
Ponzio
Gazz. Chim. Ital.,
1923
8.
Williams M.M., McEwan W.S., Henry R.A.
The Journal of Physical Chemistry,
1957