Home / Publications / New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes

New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes

Viktor Nikolaevich Nemykin 1
Viktor Nikolaevich Nemykin
, 
Nikita Borisovich Subbotin 1
Nikita Borisovich Subbotin
, 
Nina Anatol'evna Kostromina 1
Nina Anatol'evna Kostromina
, 
Sergey Vasil'evich Volkov 1
Sergey Vasil'evich Volkov
1 V.I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
10.1070/MC1995v005n02ABEH000464
Published 1995-04-30
Communication , Volume 5, Issue 2, 71-72
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Nemykin V. N. et al. New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 71-72.
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Nemykin V. N., Subbotin N. B., Kostromina N. A., Volkov S. V. New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 71-72.
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TY - JOUR
DO - 10.1070/MC1995v005n02ABEH000464
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000464
TI - New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes
T2 - Mendeleev Communications
AU - Nemykin, Viktor Nikolaevich
AU - Subbotin, Nikita Borisovich
AU - Kostromina, Nina Anatol'evna
AU - Volkov, Sergey Vasil'evich
PY - 1995
DA - 1995/04/30
PB - Mendeleev Communications
SP - 71-72
IS - 2
VL - 5
ER -
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@article{1995_Nemykin,
author = {Viktor Nikolaevich Nemykin and Nikita Borisovich Subbotin and Nina Anatol'evna Kostromina and Sergey Vasil'evich Volkov},
title = {New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000464},
number = {2},
pages = {71--72},
doi = {10.1070/MC1995v005n02ABEH000464}
}
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Nemykin, Viktor Nikolaevich, et al. “New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes.” Mendeleev Communications, vol. 5, no. 2, Apr. 1995, pp. 71-72. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000464.

Abstract

The reaction between tetraphenylphthalonitrile and 4-phthalonitrile or 6-tert-butylnaphthalonitrile in the presence of copper(I) chloride gives a non-statistical mixture of non-symmetrical phthalocyanines from which 2:2 complexes are separated; in the reaction between substituted phthalo- and naphthalonitriles the 2:2 complex was a major product. The splitting of the Q-band in the electronic spectra depends on the differences in the electronic structure of the fragments of the non-symmetrical molecule.

References

1.
10.1070/MC1995v005n02ABEH000464_bib1
Phthalocyanines: Properties Applications, 1989
2.
E. A. Luk’yanets, Elektronnye spektry ftalotsianinov i rodstvennykh soedinenii (Electronic spectra of phthalocyanines and related compounds), Cherkassy, 1989 (in Russian).
3.
New route to unsymmetrical phthalocyanine analogs by the use of structurally distorted subphthalocyanines
Kobayashi N., Kondo R., Nakajima S., Osa T.
Journal of the American Chemical Society, 1990
5.
Dimeric substituted copper phthalocyanine liquid crystals. Synthesis, characterization and magnetic properties
Lelievre D., Bosio L., Simon J., Andre J.J., Bensebaa F.
Journal of the American Chemical Society, 1992
6.
Subbotin N.B., Nemykin V.N., Voloshin Y.Z.
Mendeleev Communications, 1993
7.
Aromatization of the Diels-Alder Adduct of Tetraphenylcyclopentadienone and Fumaronitrile1
DOERING R.F., MINER R.S., ROTHMAN L., BECKER E.I.
Journal of Organic Chemistry, 1958
8.
10.1070/MC1995v005n02ABEH000464_bib8
Kovshev
Zh. Obshch. Khim., 1972
9.
10.1070/MC1995v005n02ABEH000464_bib9
Negrimovsky
Zh. Obshch. Khim., 1989
10.
10.1070/MC1995v005n02ABEH000464_bib10
Goutermann
1978