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Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid

Mikhail Victorovich Gorelik 1
Mikhail Victorovich Gorelik
, 
Vera Ivanovna Lomzakova 1
Vera Ivanovna Lomzakova
, 
Elena Azamatovna Khamidova 1
Elena Azamatovna Khamidova
, 
Vitalii Yakovlevich Shteiman 1
Vitalii Yakovlevich Shteiman
, 
Marianna Gennad'evna Kuznetsova 1
Marianna Gennad'evna Kuznetsova
, 
Alexander Mikhailovich Andrievsky 1
Alexander Mikhailovich Andrievsky
10.1070/MC1995v005n02ABEH000460
Published 1995-04-30
Communication , Volume 5, Issue 2, 65-66
3
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Gorelik M. V. et al. Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 65-66.
GOST all authors (up to 50) Copy
Gorelik M. V., Lomzakova V. I., Khamidova E. A., Shteiman V. Y., Kuznetsova M. G., Andrievsky A. M. Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 65-66.
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TY - JOUR
DO - 10.1070/MC1995v005n02ABEH000460
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000460
TI - Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid
T2 - Mendeleev Communications
AU - Gorelik, Mikhail Victorovich
AU - Lomzakova, Vera Ivanovna
AU - Khamidova, Elena Azamatovna
AU - Shteiman, Vitalii Yakovlevich
AU - Kuznetsova, Marianna Gennad'evna
AU - Andrievsky, Alexander Mikhailovich
PY - 1995
DA - 1995/04/30
PB - Mendeleev Communications
SP - 65-66
IS - 2
VL - 5
ER -
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@article{1995_Gorelik,
author = {Mikhail Victorovich Gorelik and Vera Ivanovna Lomzakova and Elena Azamatovna Khamidova and Vitalii Yakovlevich Shteiman and Marianna Gennad'evna Kuznetsova and Alexander Mikhailovich Andrievsky},
title = {Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000460},
number = {2},
pages = {65--66},
doi = {10.1070/MC1995v005n02ABEH000460}
}
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Gorelik, Mikhail Victorovich, et al. “Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid.” Mendeleev Communications, vol. 5, no. 2, Apr. 1995, pp. 65-66. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000460.

Abstract

Reaction of aniline, o- and m-substituted anilines or N,N-dialkylanilines with bromine and nitrosonium hydrogensulfate in concentrated sulfuric acid leads to the corresponding 4-bromoanilines but no bromination takes place in the absence of nitrosonium salt.

References

1.
Gorelik M.V., Lomzakova V.I., Khamidova E.A., Shteiman V.Y., Kuznetsova M.G.
Mendeleev Communications, 1995
2.
The nitration of the NN-dimethylanilinium ion. A new mechanism for catalysis by nitrous acid
Giffney J.C., Ridd J.H.
Journal of the Chemical Society Perkin Transactions 2, 1979
3.
Allan Z.J., Podstata J., Šnobl D., Jarkovský J.
Collection of Czechoslovak Chemical Communications, 2013
4.
10.1070/MC1995v005n02ABEH000460_bib4
Ridd
Adv. Phys. Org. Chem., 1978