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A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Galina Valentinovna Kryshtal 1
Galina Valentinovna Kryshtal
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
10.1070/MC1995v005n02ABEH000448
Published 1995-04-30
Communication , Volume 5, Issue 2, 41-42
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Vasil'ev A. A., Kryshtal G. V., Serebryakov E. P. A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 41-42.
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Vasil'ev A. A., Kryshtal G. V., Serebryakov E. P. A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality // Mendeleev Communications. 1995. Vol. 5. No. 2. pp. 41-42.
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TY - JOUR
DO - 10.1070/MC1995v005n02ABEH000448
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000448
TI - A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Kryshtal, Galina Valentinovna
AU - Serebryakov, Edward Prokof'evich
PY - 1995
DA - 1995/04/30
PB - Mendeleev Communications
SP - 41-42
IS - 2
VL - 5
ER -
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@article{1995_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Galina Valentinovna Kryshtal and Edward Prokof'evich Serebryakov},
title = {A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000448},
number = {2},
pages = {41--42},
doi = {10.1070/MC1995v005n02ABEH000448}
}
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Vasil'ev, Andrei Alexandrovich, et al. “A Convenient Protocol for the Stereocontrolled Synthesis of Olefins with a Homoallylic Type of Functionality.” Mendeleev Communications, vol. 5, no. 2, Apr. 1995, pp. 41-42. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n02ABEH000448.

Abstract

A combination of the Homer–Emmons synthesis of alkyl 2,4-dienoates with their hydrogenation over complex L·Cr(CO)3 catalysts (L = arene or 3CO) provides a versatile, stereocontrolled approach to olefins with a homoallylic pattern of functional substitution, such as certain insect pheromones or (Z)-prenylated arenes analogous to the “left-side” moiety of bifurcarenone.

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