Home / Publications / Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines

Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines

Lambert Brandsma 1
Lambert Brandsma
, 
Johanes A van Doorn 2
Johanes A van Doorn
, 
Robert-Jan de Lang 1
Robert-Jan de Lang
, 
Nina Kuzminichna Gusarova 3
Nina Kuzminichna Gusarova
, 
Trofim Ivanovich Trofimov 4
Trofim Ivanovich Trofimov
10.1070/MC1995v005n01ABEH000438
Published 1995-02-28
Communication , Volume 5, Issue 1, 14-15
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Brandsma L. et al. Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines // Mendeleev Communications. 1995. Vol. 5. No. 1. pp. 14-15.
GOST all authors (up to 50) Copy
Brandsma L., van Doorn J. A., de Lang R., Gusarova N. K., Trofimov T. I. Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines // Mendeleev Communications. 1995. Vol. 5. No. 1. pp. 14-15.
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TY - JOUR
DO - 10.1070/MC1995v005n01ABEH000438
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000438
TI - Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines
T2 - Mendeleev Communications
AU - Brandsma, Lambert
AU - van Doorn, Johanes A
AU - de Lang, Robert-Jan
AU - Gusarova, Nina Kuzminichna
AU - Trofimov, Trofim Ivanovich
PY - 1995
DA - 1995/02/28
PB - Mendeleev Communications
SP - 14-15
IS - 1
VL - 5
ER -
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@article{1995_Brandsma,
author = {Lambert Brandsma and Johanes A van Doorn and Robert-Jan de Lang and Nina Kuzminichna Gusarova and Trofim Ivanovich Trofimov},
title = {Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000438},
number = {1},
pages = {14--15},
doi = {10.1070/MC1995v005n01ABEH000438}
}
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Brandsma, Lambert, et al. “Cleavage of P–P Bonds in Phosphorus. An Efficient Method for the Preparation of Primary Alkylphosphines.” Mendeleev Communications, vol. 5, no. 1, Feb. 1995, pp. 14-15. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000438.

Abstract

Effective cleavage of P–P bonds in red (and yellow) phosphorus can be brought about by adding tert-butyl alcohol to a mixture of phosphorus, lithium and liquid ammonia; subsequent addition of alkyl halides gives primary phosphines in good to excellent yields.

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