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A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles

Andrei Olegovich Koren 1
Andrei Olegovich Koren
, 
Pavel Nikolaevich Gaponik 1
Pavel Nikolaevich Gaponik
, 
Oleg Anatol'evich Ivashkevich 1
Oleg Anatol'evich Ivashkevich
, 
Tamara B Kovalyova 1
Tamara B Kovalyova
10.1070/MC1995v005n01ABEH000435
Published 1995-02-28
Communication , Volume 5, Issue 1, 10-11
11
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Koren A. O. et al. A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles // Mendeleev Communications. 1995. Vol. 5. No. 1. pp. 10-11.
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Koren A. O., Gaponik P. N., Ivashkevich O. A., Kovalyova T. B. A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles // Mendeleev Communications. 1995. Vol. 5. No. 1. pp. 10-11.
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TY - JOUR
DO - 10.1070/MC1995v005n01ABEH000435
UR - https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000435
TI - A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles
T2 - Mendeleev Communications
AU - Koren, Andrei Olegovich
AU - Gaponik, Pavel Nikolaevich
AU - Ivashkevich, Oleg Anatol'evich
AU - Kovalyova, Tamara B
PY - 1995
DA - 1995/02/28
PB - Mendeleev Communications
SP - 10-11
IS - 1
VL - 5
ER -
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@article{1995_Koren,
author = {Andrei Olegovich Koren and Pavel Nikolaevich Gaponik and Oleg Anatol'evich Ivashkevich and Tamara B Kovalyova},
title = {A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles},
journal = {Mendeleev Communications},
year = {1995},
volume = {5},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000435},
number = {1},
pages = {10--11},
doi = {10.1070/MC1995v005n01ABEH000435}
}
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Koren, Andrei Olegovich, et al. “A New Route to 1-Alkyltetrazoles: via 2-tert-Butyltetrazoles.” Mendeleev Communications, vol. 5, no. 1, Feb. 1995, pp. 10-11. https://mendcomm.colab.ws/publications/10.1070/MC1995v005n01ABEH000435.

Abstract

1-Alkyl-5-R-tetrazoles, free of the corresponding 2-isomers, can be readily obtained in high yield from 5-R-tetrazoles via exhaustive alkylation of their readily available 2-tert-butyl derivatives followed by removal of the tert-butyl group from the 1(4)-alkyl-3(2)-tert-butyl-5-R-tetrazolium salts formed.

References

1.
10.1070/MC1995v005n01ABEH000435_bib1
Butler
1984
3.
t-butylation of 5-substituted tetrazoles
Henry R.A.
Journal of Heterocyclic Chemistry, 1976
5.
Regiospecific coordination of ambidentate tetrazoles to cobalt oximes
Takach N.E., Holt E.M., Alcock N.W., Henry R.A., Nelson J.H.
Journal of the American Chemical Society, 1980
7.
10.1070/MC1995v005n01ABEH000435_bib6
Koren
Khim. Geterotsikl. Soedin., 1990
8.
10.1070/MC1995v005n01ABEH000435_bib7_1
Zhivich
Khim. Geterotsikl. Soedin., 1990
9.
1H, 13C and 15N NMR study of vinyltetrazolium salts and processes of their synthesis
Gaponik P.N., Ivashkevish O.A., Naumenko V.N., Kovalyova T.B., Andreeva T.N., Koren A.O.
Spectrochimica Acta Part A Molecular Spectroscopy, 1993
10.
Notes. N-Vinyl-tetrazoles
Finnegan W., Henry R.
Journal of Organic Chemistry, 1959
11.
10.1070/MC1995v005n01ABEH000435_bib9
Gaponik
Teor. Eksp. Khim., 1989
12.
R. A. Henry, US Patent 3351627, 1967.