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Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane

Mikhail Evguen'evich Gurskii 1
Mikhail Evguen'evich Gurskii
, 
Ilya Dmitrievich Gridnev 1
Ilya Dmitrievich Gridnev
, 
Alexei Viktorovich Buevich 1
Alexei Viktorovich Buevich
, 
Tamara Vladimirovna Potapova 1
Tamara Vladimirovna Potapova
, 
Vadim Izrailevich Mstislavsky 1
Vadim Izrailevich Mstislavsky
, 
Anatoly O Krasavin 2
Anatoly O Krasavin
, 
Yurii Nikolaevich Bubnov 1
Yurii Nikolaevich Bubnov
10.1070/MC1994v004n06ABEH000424
Published 1994-12-31
Communication , Volume 4, Issue 6, 221-223
2
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Gurskii M. E. et al. Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane // Mendeleev Communications. 1994. Vol. 4. No. 6. pp. 221-223.
GOST all authors (up to 50) Copy
Gurskii M. E., Gridnev I. D., Buevich A. V., Potapova T. V., Mstislavsky V. I., Krasavin A. O., Bubnov Y. N. Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane // Mendeleev Communications. 1994. Vol. 4. No. 6. pp. 221-223.
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TY - JOUR
DO - 10.1070/MC1994v004n06ABEH000424
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000424
TI - Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane
T2 - Mendeleev Communications
AU - Gurskii, Mikhail Evguen'evich
AU - Gridnev, Ilya Dmitrievich
AU - Buevich, Alexei Viktorovich
AU - Potapova, Tamara Vladimirovna
AU - Mstislavsky, Vadim Izrailevich
AU - Krasavin, Anatoly O
AU - Bubnov, Yurii Nikolaevich
PY - 1994
DA - 1994/12/31
PB - Mendeleev Communications
SP - 221-223
IS - 6
VL - 4
ER -
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@article{1994_Gurskii,
author = {Mikhail Evguen'evich Gurskii and Ilya Dmitrievich Gridnev and Alexei Viktorovich Buevich and Tamara Vladimirovna Potapova and Vadim Izrailevich Mstislavsky and Anatoly O Krasavin and Yurii Nikolaevich Bubnov},
title = {Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000424},
number = {6},
pages = {221--223},
doi = {10.1070/MC1994v004n06ABEH000424}
}
MLA
Cite this
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Gurskii, Mikhail Evguen'evich, et al. “Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane.” Mendeleev Communications, vol. 4, no. 6, Dec. 1994, pp. 221-223. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000424.

Abstract

Cyclooctatetraenyldipropylborane 4 has been synthesized in 47% yield; activation parameters for bond shifting in 4 determined by lineshape analysis of the 13C NMR spectra are ΔG╪(298) = 67.7±0.1 kJ mol−1; ΔH╪ = 58.1±0.8 kJ mol−1; ΔS╪ = –32±5 kJ mol−1 K−1.

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