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The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K

Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
, 
Viktor Adol'fovich Benderskii 1
Viktor Adol'fovich Benderskii
, 
Albert Udovich Goldschleger 1
Albert Udovich Goldschleger
, 
Alexander Vladimirovich Akimov 1
Alexander Vladimirovich Akimov
10.1070/MC1994v004n06ABEH000413
Published 1994-12-31
Communication , Volume 4, Issue 6, 203-204
3
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Misochko E. Y. et al. The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K // Mendeleev Communications. 1994. Vol. 4. No. 6. pp. 203-204.
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Misochko E. Y., Benderskii V. A., Goldschleger A. U., Akimov A. V. The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K // Mendeleev Communications. 1994. Vol. 4. No. 6. pp. 203-204.
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TY - JOUR
DO - 10.1070/MC1994v004n06ABEH000413
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000413
TI - The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K
T2 - Mendeleev Communications
AU - Misochko, Evgenii Yakovlevich
AU - Benderskii, Viktor Adol'fovich
AU - Goldschleger, Albert Udovich
AU - Akimov, Alexander Vladimirovich
PY - 1994
DA - 1994/12/31
PB - Mendeleev Communications
SP - 203-204
IS - 6
VL - 4
ER -
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@article{1994_Misochko,
author = {Evgenii Yakovlevich Misochko and Viktor Adol'fovich Benderskii and Albert Udovich Goldschleger and Alexander Vladimirovich Akimov},
title = {The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000413},
number = {6},
pages = {203--204},
doi = {10.1070/MC1994v004n06ABEH000413}
}
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Misochko, Evgenii Yakovlevich, et al. “The Formation of Pairs of Widely Spaced Methyl Radicals following Fluorine Photolysis in Solid Methane at 10–15 K.” Mendeleev Communications, vol. 4, no. 6, Dec. 1994, pp. 203-204. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n06ABEH000413.

Abstract

Quantum yields of CH3 radicals (YR = 0.95±0.2) and CH3F…F complexes (Yo = 0.6±0.1), formed by UV photolysis in CH4–F2 solid mixtures (70:1), have been measured using EPR and IR spectroscopy. Since 12YR+Y0≅1, fluorine atoms do not recombine in a cage; approximately half of them are involved in formation of the complexes while the rest gives CH3 radical pairs. The fraction of pairs with an inter-radical spacing >20 Å is 0.1–0.15.

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