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A Mechanism for Selectivity in Heterogeneous Redox Catalysis

Vitalii Vital'evich Gavrik 1
Vitalii Vital'evich Gavrik
10.1070/MC1994v004n05ABEH000412
Published 1994-10-30
Communication , Volume 4, Issue 5, 191-193
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Gavrik V. V. A Mechanism for Selectivity in Heterogeneous Redox Catalysis // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 191-193.
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Gavrik V. V. A Mechanism for Selectivity in Heterogeneous Redox Catalysis // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 191-193.
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TY - JOUR
DO - 10.1070/MC1994v004n05ABEH000412
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000412
TI - A Mechanism for Selectivity in Heterogeneous Redox Catalysis
T2 - Mendeleev Communications
AU - Gavrik, Vitalii Vital'evich
PY - 1994
DA - 1994/10/30
PB - Mendeleev Communications
SP - 191-193
IS - 5
VL - 4
ER -
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@article{1994_Gavrik,
author = {Vitalii Vital'evich Gavrik},
title = {A Mechanism for Selectivity in Heterogeneous Redox Catalysis},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000412},
number = {5},
pages = {191--193},
doi = {10.1070/MC1994v004n05ABEH000412}
}
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Gavrik, Vitalii Vital'evich. “A Mechanism for Selectivity in Heterogeneous Redox Catalysis.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 191-193. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000412.

Abstract

Selective acceleration of metal cation oxidation by silver halide in the presence of silver nanoclusters is observed only when the diameters of the cations correspond to the spacing of the regularset of interatomic hollows of the catalyst surface; this is probably associated with their longer retention in the reaction zone due to the increase in the coordination number in the coincidentally occurring compact packing.

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