Home / Articles / Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

Oleg Evgenevich Nasakin 1
Oleg Evgenevich Nasakin
, 
Petr Matveevich Lukin 1
Petr Matveevich Lukin
, 
Evgenii Vladimirovich Vershinin 1
Evgenii Vladimirovich Vershinin
, 
Sergei Vitalyevich Lindeman 2
Sergei Vitalyevich Lindeman
, 
Yuri Timofeevich Struchkov 2
Yuri Timofeevich Struchkov
10.1070/MC1994v004n05ABEH000407
Published 30 October 1994 , received 25 April 1994
Communication , Volume 4, Issue 5, 185-186
5
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Nasakin O. E. et al. Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 185-186.
GOST all authors (up to 50)
Copy cite
Nasakin O. E., Lukin P. M., Vershinin E. V., Lindeman S. V., Struchkov Y. T. Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 185-186.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.1070/MC1994v004n05ABEH000407
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407
TI - Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles
T2 - Mendeleev Communications
AU - Nasakin, Oleg Evgenevich
AU - Lukin, Petr Matveevich
AU - Vershinin, Evgenii Vladimirovich
AU - Lindeman, Sergei Vitalyevich
AU - Struchkov, Yuri Timofeevich
PY - 1994
DA - 1994/10/30
PB - Mendeleev Communications
SP - 185-186
IS - 5
VL - 4
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{1994_Nasakin,
author = {Oleg Evgenevich Nasakin and Petr Matveevich Lukin and Evgenii Vladimirovich Vershinin and Sergei Vitalyevich Lindeman and Yuri Timofeevich Struchkov},
title = {Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407},
number = {5},
pages = {185--186},
doi = {10.1070/MC1994v004n05ABEH000407}
}
MLA
Cite this
MLA
Copy cite
Nasakin, Oleg Evgenevich, et al. “Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 185-186. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407.
Views / Visits / Downloads
34 / 34 / 57

Abstract

Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 was established by an X-ray crystallographic study.

References

1.
Anisimov V.M., Zolotoi A.B., Antipin M.Y., Lukin P.M., Nasakin O.E., Struchkov Y.T.
Mendeleev Communications, 1992
2.
10.1070/MC1994v004n05ABEH000407_bib2
Robinson
Crystallographic Computing Techniques and New Technologies, 1988
3.
Cyanocarbon Chemistry. V.1 Cyanocarbon Acids and their Salts
Middleton W.J., Little E.L., Coffman D.D., Engelhardt V.A.
Journal of the American Chemical Society, 1958
4.
Tetracyanoethylene Oxide. I. Preparation and Reaction with Nucleophiles1
Linn W.J., Webster O.W., Benson R.E.
Journal of the American Chemical Society, 1965