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Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

Oleg Evgenevich Nasakin ¹

Oleg Evgenevich Nasakin

Petr Matveevich Lukin ¹

Petr Matveevich Lukin

Evgenii Vladimirovich Vershinin ¹

Evgenii Vladimirovich Vershinin

Sergei Vitalyevich Lindeman ²

Sergei Vitalyevich Lindeman

Yuri Timofeevich Struchkov ²

Yuri Timofeevich Struchkov

¹ Department of Chemistry, I.N. Ulyanov Chuvash State University, Cheboksary, Russian Federation

² A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1070/MC1994v004n05ABEH000407

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Published 1994-10-30

Communication , Volume 4, Issue 5, 185-186

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Nasakin O. E. et al. Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 185-186.

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Nasakin O. E., Lukin P. M., Vershinin E. V., Lindeman S. V., Struchkov Y. T. Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 185-186.

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TY - JOUR

DO - 10.1070/MC1994v004n05ABEH000407

UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407

TI - Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

T2 - Mendeleev Communications

AU - Nasakin, Oleg Evgenevich

AU - Lukin, Petr Matveevich

AU - Vershinin, Evgenii Vladimirovich

AU - Lindeman, Sergei Vitalyevich

AU - Struchkov, Yuri Timofeevich

PY - 1994

DA - 1994/10/30

PB - Mendeleev Communications

SP - 185-186

IS - 5

VL - 4

ER -

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@article{1994_Nasakin,

author = {Oleg Evgenevich Nasakin and Petr Matveevich Lukin and Evgenii Vladimirovich Vershinin and Sergei Vitalyevich Lindeman and Yuri Timofeevich Struchkov},

title = {Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles},

journal = {Mendeleev Communications},

year = {1994},

volume = {4},

publisher = {Mendeleev Communications},

month = {Oct},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407},

number = {5},

pages = {185--186},

doi = {10.1070/MC1994v004n05ABEH000407}

}

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Nasakin, Oleg Evgenevich, et al. “Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 185-186. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000407.

Abstract

Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 was established by an X-ray crystallographic study.

References

10.1070/MC1992v002n01ABEH000107

Hexacyanocyclopropane. Synthesis and Structure

Anisimov V.M., Zolotoi A.B., Antipin M.Y., Lukin P.M., Nasakin O.E., Struchkov Y.T.

Mendeleev Communications, 1992

10.1070/MC1994v004n05ABEH000407_bib2

Robinson

Crystallographic Computing Techniques and New Technologies, 1988

10.1021/ja01544a055

Cyanocarbon Chemistry. V.¹ Cyanocarbon Acids and their Salts

Middleton W.J., Little E.L., Coffman D.D., Engelhardt V.A.

Journal of the American Chemical Society, 1958

10.1021/ja01094a022

Tetracyanoethylene Oxide. I. Preparation and Reaction with Nucleophiles¹

Linn W.J., Webster O.W., Benson R.E.

Journal of the American Chemical Society, 1965