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Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3

Stanislav Zbignevovich Bernadyuk 1
Stanislav Zbignevovich Bernadyuk
, 
Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Mark Efimovich Vol'pin 1
Mark Efimovich Vol'pin
10.1070/MC1994v004n05ABEH000406
Published 1994-10-30
Communication , Volume 4, Issue 5, 183-185
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Bernadyuk S. Z., Akhrem I. S., Vol'pin M. E. Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3 // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 183-185.
GOST all authors (up to 50) Copy
Bernadyuk S. Z., Akhrem I. S., Vol'pin M. E. Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3 // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 183-185.
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TY - JOUR
DO - 10.1070/MC1994v004n05ABEH000406
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000406
TI - Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3
T2 - Mendeleev Communications
AU - Bernadyuk, Stanislav Zbignevovich
AU - Akhrem, Irena Sergeevna
AU - Vol'pin, Mark Efimovich
PY - 1994
DA - 1994/10/30
PB - Mendeleev Communications
SP - 183-185
IS - 5
VL - 4
ER -
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@article{1994_Bernadyuk,
author = {Stanislav Zbignevovich Bernadyuk and Irena Sergeevna Akhrem and Mark Efimovich Vol'pin},
title = {Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000406},
number = {5},
pages = {183--185},
doi = {10.1070/MC1994v004n05ABEH000406}
}
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Bernadyuk, Stanislav Zbignevovich, et al. “Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 183-185. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000406.

Abstract

The aprotic organic superacid CBr4·2AIBr3 initiates carbonylation of methylcyclopentane 1 and cyclohexane 2 with CO at atmospheric pressure with formation (after EtOH treatment) of various products in high yields depending on the conditions. The products are esters of 1-methylcyclopentanecarbonic (1a; at −45 °C) and cyclohexanecarbonic (2a; at 0°C) acids and 2-methylcyclohexanone (3; at − 23 °C); the reaction mechanism is discussed.

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