Home / Publications / Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene

Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene

Tamara Stepanovna Kuznetsova 1
Tamara Stepanovna Kuznetsova
, 
Olga Vladimirovna Eremenko 1
Olga Vladimirovna Eremenko
, 
Olga Vladimirovna Kokoreva 1
Olga Vladimirovna Kokoreva
, 
Georgy Valer'evich Zatonsky 2
Georgy Valer'evich Zatonsky
, 
Nikolai Serafimovich Zefirov 1
Nikolai Serafimovich Zefirov
10.1070/MC1994v004n05ABEH000399
Published 1994-10-30
Communication , Volume 4, Issue 5, 172-172
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kuznetsova T. S. et al. Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 172-172.
GOST all authors (up to 50) Copy
Kuznetsova T. S., Eremenko O. V., Kokoreva O. V., Zatonsky G. V., Zefirov N. S. Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 172-172.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1994v004n05ABEH000399
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000399
TI - Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene
T2 - Mendeleev Communications
AU - Kuznetsova, Tamara Stepanovna
AU - Eremenko, Olga Vladimirovna
AU - Kokoreva, Olga Vladimirovna
AU - Zatonsky, Georgy Valer'evich
AU - Zefirov, Nikolai Serafimovich
PY - 1994
DA - 1994/10/30
PB - Mendeleev Communications
SP - 172-172
IS - 5
VL - 4
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1994_Kuznetsova,
author = {Tamara Stepanovna Kuznetsova and Olga Vladimirovna Eremenko and Olga Vladimirovna Kokoreva and Georgy Valer'evich Zatonsky and Nikolai Serafimovich Zefirov},
title = {Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000399},
number = {5},
pages = {172--172},
doi = {10.1070/MC1994v004n05ABEH000399}
}
MLA
Cite this
MLA Copy
Kuznetsova, Tamara Stepanovna, et al. “Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 172-172. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000399.

Abstract

Synthesis of pentacyclo[9.1.0.01 3.03.5.05.7]dodecane 4 and hexacyclo[10.1.0.01 3.03.5.05.7.07.9]tridecane 5 has been performed, based on sequential bromocyclopropanation of the C=C bond and elimination to give a repeating endomethylenecyclopropane framework, with termination of the sequence by cyclopropanation.

References

1.
Triangulanes: stereoisomerism and general method of synthesis
Zefirov N.S., Kozhushkov S.I., Kuznetsova T.S., Kokoreva O.V., Lukin K.A., Ugrak B.I., Tratch S.S.
Journal of the American Chemical Society, 1990
2.
10.1070/MC1994v004n05ABEH000399_bib1_2
Zefirov
Zh. Org. Khim., 1989
3.
The synthesis of bismethylene derivatives of triangulanes
Lukin K.A., Masunova A.Y., Ugrak B.I., Zefirov N.S.
Tetrahedron, 1991
4.
Lukin K.A., Kozhushkov S.I., Andrievski A.A., Ugrak B.I., Zefirov N.S.
Mendeleev Communications, 1992
5.
Synthesis of branched triangulanes
Lukin K.A., Kozhushkov S.I., Andrievskii A.A., Ugrak B.I., Zefirov N.S.
Journal of Organic Chemistry, 1991
6.
Branched triangulanes: general strategy of synthesis
Zefirov N.S., Kozhushkov S.I., Ugrak B.I., Lukin K.A., Kokoreva O.V., Yufit D.S., Struchkov Y.T., Zoellner S., Boese R., De Meijere A.
Journal of Organic Chemistry, 1992
7.
A new general approach to bicyclopropylidenes
De Meijere A., Kozhushkov S.I., Spaeth T., Zefirov N.S.
Journal of Organic Chemistry, 1993
8.
Preparation of functionally substituted bicyclopropylidenes
de Meijere A., Kozhushkov S.I., Zefirov N.S.
Synthesis, 1993
9.
7,7′-Bi(dispiro[2.0.2.1]heptyliden) - das perspirocyclopropanierte Bicyclopropyliden†‡
Zöllner S., Buchholz H., Boese R., Gleiter R., de Meijere A.
Angewandte Chemie, 1991
10.
Zefirov N.S., Kuznetsova T.S., Eremenko O.V., Kokoreva O.V.
Mendeleev Communications, 1993
11.
Sequential Peripheral Cyclopropanation as a Synthetic Approach to Cyclosubstituted Triangulanes
Zefirov N.S., Kuznetsova T.S., Eremenko O.V., Kokoreva O.V., Zatonsky G., Ugrak B.I.
Journal of Organic Chemistry, 1994