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The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10

Alexander Yakovlevich Usiatinsky 1
Alexander Yakovlevich Usiatinsky
, 
Olga Mikhailovna Khitrova 1
Olga Mikhailovna Khitrova
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
, 
Fedor Mikhailovich Dolgushin 1
Fedor Mikhailovich Dolgushin
, 
Aleksandr Il'ich Yanovsky 1
Aleksandr Il'ich Yanovsky
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
, 
Vladimir Iosifovich Bregadze 1
Vladimir Iosifovich Bregadze
10.1070/MC1994v004n05ABEH000398
Published 1994-10-30
Communication , Volume 4, Issue 5, 169-171
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Usiatinsky A. Y. et al. The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10 // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 169-171.
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Usiatinsky A. Y., Khitrova O. M., Petrovskii P. V., Dolgushin F. M., Yanovsky A. I., Struchkov Y. T., Bregadze V. I. The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10 // Mendeleev Communications. 1994. Vol. 4. No. 5. pp. 169-171.
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TY - JOUR
DO - 10.1070/MC1994v004n05ABEH000398
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000398
TI - The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10
T2 - Mendeleev Communications
AU - Usiatinsky, Alexander Yakovlevich
AU - Khitrova, Olga Mikhailovna
AU - Petrovskii, Pavel Vasil'evich
AU - Dolgushin, Fedor Mikhailovich
AU - Yanovsky, Aleksandr Il'ich
AU - Struchkov, Yuri Timofeevich
AU - Bregadze, Vladimir Iosifovich
PY - 1994
DA - 1994/10/30
PB - Mendeleev Communications
SP - 169-171
IS - 5
VL - 4
ER -
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@article{1994_Usiatinsky,
author = {Alexander Yakovlevich Usiatinsky and Olga Mikhailovna Khitrova and Pavel Vasil'evich Petrovskii and Fedor Mikhailovich Dolgushin and Aleksandr Il'ich Yanovsky and Yuri Timofeevich Struchkov and Vladimir Iosifovich Bregadze},
title = {The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000398},
number = {5},
pages = {169--171},
doi = {10.1070/MC1994v004n05ABEH000398}
}
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Usiatinsky, Alexander Yakovlevich, et al. “The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10.” Mendeleev Communications, vol. 4, no. 5, Oct. 1994, pp. 169-171. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n05ABEH000398.

Abstract

The interaction of equivalent amounts of 3,6-Cp2-3,6,1,2-Co2C2B8H10 1 and mercury(II) acetate in boiling CH2CI2 followed by treatment with NaCI results in a mixture (1:1.2) of 8- and 9-chloromercury derivatives of dicobaltacarboranes (compounds 2 and 3). The action of excess Hg(OAc)2 on 1 leads to the tetramercurated compound with substitution in positions 8, 9, 10 and 12 of the carborane icosahedron; the structure of 8-CIHg-3,6-Cp2-3,6,1,2-Co2C2B8H9 was determined by an X-ray diffraction study.

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