Home / Publications / Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution

Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution

Irina Yur'evna Bagryanskaya 1
Irina Yur'evna Bagryanskaya
, 
Yuriy Vasil'evich Gatilov 1
Yuriy Vasil'evich Gatilov
, 
Makhmut Minakhmetovich Shakirov 1
Makhmut Minakhmetovich Shakirov
, 
Andrey Viktorovich Zibarev 1
Andrey Viktorovich Zibarev
10.1070/MC1994v004n04ABEH000385
Published 1994-08-31
Communication , Volume 4, Issue 4, 136-137
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Bagryanskaya I. Y. et al. Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution // Mendeleev Communications. 1994. Vol. 4. No. 4. pp. 136-137.
GOST all authors (up to 50) Copy
Bagryanskaya I. Y., Gatilov Y. V., Shakirov M. M., Zibarev A. V. Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution // Mendeleev Communications. 1994. Vol. 4. No. 4. pp. 136-137.
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TY - JOUR
DO - 10.1070/MC1994v004n04ABEH000385
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n04ABEH000385
TI - Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution
T2 - Mendeleev Communications
AU - Bagryanskaya, Irina Yur'evna
AU - Gatilov, Yuriy Vasil'evich
AU - Shakirov, Makhmut Minakhmetovich
AU - Zibarev, Andrey Viktorovich
PY - 1994
DA - 1994/08/31
PB - Mendeleev Communications
SP - 136-137
IS - 4
VL - 4
ER -
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@article{1994_Bagryanskaya,
author = {Irina Yur'evna Bagryanskaya and Yuriy Vasil'evich Gatilov and Makhmut Minakhmetovich Shakirov and Andrey Viktorovich Zibarev},
title = {Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n04ABEH000385},
number = {4},
pages = {136--137},
doi = {10.1070/MC1994v004n04ABEH000385}
}
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Bagryanskaya, Irina Yur'evna, et al. “Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution.” Mendeleev Communications, vol. 4, no. 4, Aug. 1994, pp. 136-137. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n04ABEH000385.

Abstract

It has been shown by X-ray structure analysis, 1H NMR spectroscopy (including NOE) and PM3 calculations that symmetric isomers of the title compounds in the crystal and in solution have a Z,Z configuration stabilized by nN,π interaction, but not the E,E configuration suggested earlier.

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