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Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine

Sergei Viktorovich Chapyshev 1
Sergei Viktorovich Chapyshev
, 
Toshikazu Ibata 2
Toshikazu Ibata
10.1070/MC1994v004n03ABEH000373
Published 1994-06-30
Communication , Volume 4, Issue 3, 109-110
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Chapyshev S. V., Ibata T. Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine // Mendeleev Communications. 1994. Vol. 4. No. 3. pp. 109-110.
GOST all authors (up to 50) Copy
Chapyshev S. V., Ibata T. Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine // Mendeleev Communications. 1994. Vol. 4. No. 3. pp. 109-110.
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TY - JOUR
DO - 10.1070/MC1994v004n03ABEH000373
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000373
TI - Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine
T2 - Mendeleev Communications
AU - Chapyshev, Sergei Viktorovich
AU - Ibata, Toshikazu
PY - 1994
DA - 1994/06/30
PB - Mendeleev Communications
SP - 109-110
IS - 3
VL - 4
ER -
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@article{1994_Chapyshev,
author = {Sergei Viktorovich Chapyshev and Toshikazu Ibata},
title = {Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000373},
number = {3},
pages = {109--110},
doi = {10.1070/MC1994v004n03ABEH000373}
}
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Chapyshev, Sergei Viktorovich, and Toshikazu Ibata. “Intermediates in the Reactions of Chloranil and 2,6-Dichloro-1,4-benzoquinone with Pyrrolidine.” Mendeleev Communications, vol. 4, no. 3, Jun. 1994, pp. 109-110. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000373.

Abstract

Although the intermediates in the reactions of chloranil and 2,6-dichloro-1,4-benzoquinone with pyrrolidine are the corresponding monoaminated chloroquinones, these compounds exhibit a pronounced tendency to form molecular complexes; thus, the spectral characteristics of 2,3,5-trichloro-6-pyrrolidino-1,4-benzoquinone indicate its partial self-complexation into the corresponding biradical dimer. 2,6-Dichloro-3-pyrrolidino-1,4-benzoquinone forms a stable quinhydrone complex with 2,6-dichlorohydroquinone.

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