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Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles

Yurii Alexeevich Azev 1
Yurii Alexeevich Azev
, 
Inna P Loginova 2
Inna P Loginova
, 
Olga L Guselnikova 2
Olga L Guselnikova
, 
Sergei Victorovich Shorshnev 1
Sergei Victorovich Shorshnev
, 
Vladimir Leonidovich Rusinov 3
Vladimir Leonidovich Rusinov
, 
Oleg Nikolaevich Chupakhin 4
Oleg Nikolaevich Chupakhin
10.1070/MC1994v004n03ABEH000371
Published 1994-06-30
Communication , Volume 4, Issue 3, 104-107
7
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Azev Y. A. et al. Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 3. pp. 104-107.
GOST all authors (up to 50) Copy
Azev Y. A., Loginova I. P., Guselnikova O. L., Shorshnev S. V., Rusinov V. L., Chupakhin O. N. Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles // Mendeleev Communications. 1994. Vol. 4. No. 3. pp. 104-107.
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TY - JOUR
DO - 10.1070/MC1994v004n03ABEH000371
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000371
TI - Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles
T2 - Mendeleev Communications
AU - Azev, Yurii Alexeevich
AU - Loginova, Inna P
AU - Guselnikova, Olga L
AU - Shorshnev, Sergei Victorovich
AU - Rusinov, Vladimir Leonidovich
AU - Chupakhin, Oleg Nikolaevich
PY - 1994
DA - 1994/06/30
PB - Mendeleev Communications
SP - 104-107
IS - 3
VL - 4
ER -
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@article{1994_Azev,
author = {Yurii Alexeevich Azev and Inna P Loginova and Olga L Guselnikova and Sergei Victorovich Shorshnev and Vladimir Leonidovich Rusinov and Oleg Nikolaevich Chupakhin},
title = {Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000371},
number = {3},
pages = {104--107},
doi = {10.1070/MC1994v004n03ABEH000371}
}
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Azev, Yurii Alexeevich, et al. “Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles.” Mendeleev Communications, vol. 4, no. 3, Jun. 1994, pp. 104-107. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n03ABEH000371.

Abstract

The reaction of 2,4-diazido-s-triazines 1 with an equimolar amount or a two-fold molar excess of ethyl cyanoacetate in the presence of triethylamine in DMF affords the corresponding mono- 2 or diamino derivatives of s-triazine 3; on heating 2,4-diazido-s-triazines 1a–d with a two-fold molar excess of acetoacetone or ethyl acetoacetate in the presence of triethylamine in ethanol the corresponding 1,2,3-triazolo-s-triazines 4a–f are formed.

References

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Neuere Methoden der präparativen organischen Chemie VI. Diazogruppen-Übertragung
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Angewandte Chemie, 1967
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Ueber eine Synthese von Derivaten des 1.2.3‐Triazols
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Berichte der deutschen chemischen Gesellschaft, 1902
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10.1070/MC1994v004n03ABEH000371_bib5
Lwowski
1984