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Chain Crossing upon Solid State Methane Photofluorination at 16 K

Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
, 
Viktor Adol'fovich Benderskii 1
Viktor Adol'fovich Benderskii
, 
Albert Udovich Goldschleger 1
Albert Udovich Goldschleger
10.1070/MC1994v004n02ABEH000355
Published 1994-04-30
Communication , Volume 4, Issue 2, 71-73
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Misochko E. Y., Benderskii V. A., Goldschleger A. U. Chain Crossing upon Solid State Methane Photofluorination at 16 K // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 71-73.
GOST all authors (up to 50) Copy
Misochko E. Y., Benderskii V. A., Goldschleger A. U. Chain Crossing upon Solid State Methane Photofluorination at 16 K // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 71-73.
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TY - JOUR
DO - 10.1070/MC1994v004n02ABEH000355
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000355
TI - Chain Crossing upon Solid State Methane Photofluorination at 16 K
T2 - Mendeleev Communications
AU - Misochko, Evgenii Yakovlevich
AU - Benderskii, Viktor Adol'fovich
AU - Goldschleger, Albert Udovich
PY - 1994
DA - 1994/04/30
PB - Mendeleev Communications
SP - 71-73
IS - 2
VL - 4
ER -
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@article{1994_Misochko,
author = {Evgenii Yakovlevich Misochko and Viktor Adol'fovich Benderskii and Albert Udovich Goldschleger},
title = {Chain Crossing upon Solid State Methane Photofluorination at 16 K},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000355},
number = {2},
pages = {71--73},
doi = {10.1070/MC1994v004n02ABEH000355}
}
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Misochko, Evgenii Yakovlevich, et al. “Chain Crossing upon Solid State Methane Photofluorination at 16 K.” Mendeleev Communications, vol. 4, no. 2, Apr. 1994, pp. 71-73. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000355.

Abstract

Photolysis of solid equimolar mixtures of CH4 and F2 at 16 K leads to formation of spatially isolated CH3F, CH2F2 and HF, whereas in methane-diluted mixtures ([CH4]:[F2] = 60:1) cage formation of CH3F…HF complexes prevails; the observed quadratic relation between CH2F2 concentration and exposure dose and high quantum yield of the secondary product (per CH3F molecule formed) means that CH2F2 molecules are formed from CH3F, generated by the growth of previous chains.

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10.1070/MC1994v004n02ABEH000355_bib3
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