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Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids

Manobjyoti Bordoloi 1
Manobjyoti Bordoloi
, 
Girish M Singhal 2
Girish M Singhal
, 
Nalin B Das 3
Nalin B Das
, 
Ram P Sharma 4
Ram P Sharma
1 Natural Products Chemistry Group, Regional Research Laboratory, Assam, India
2 Atul Chemicals, Valsad, Gujrat, India
3 RRL Bhubaneswar, Bhubaneswar, Orissa, India
10.1070/MC1994v004n02ABEH000350
Published 1994-04-30
Communication , Volume 4, Issue 2, 62-64
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Bordoloi M. et al. Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 62-64.
GOST all authors (up to 50) Copy
Bordoloi M., Singhal G. M., Das N. B., Sharma R. P. Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 62-64.
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TY - JOUR
DO - 10.1070/MC1994v004n02ABEH000350
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000350
TI - Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids
T2 - Mendeleev Communications
AU - Bordoloi, Manobjyoti
AU - Singhal, Girish M
AU - Das, Nalin B
AU - Sharma, Ram P
PY - 1994
DA - 1994/04/30
PB - Mendeleev Communications
SP - 62-64
IS - 2
VL - 4
ER -
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@article{1994_Bordoloi,
author = {Manobjyoti Bordoloi and Girish M Singhal and Nalin B Das and Ram P Sharma},
title = {Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000350},
number = {2},
pages = {62--64},
doi = {10.1070/MC1994v004n02ABEH000350}
}
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Bordoloi, Manobjyoti, et al. “Stannous lodide–HCI in Tetrahydrofuran: A New System for the Reduction of various Nitro Compounds. Mild Conversion of 6-Nitro-Δ5-Steroids to 6-Keto-steroids.” Mendeleev Communications, vol. 4, no. 2, Apr. 1994, pp. 62-64. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000350.

Abstract

It has been shown that 6-nitro-Δ5-steroids, nitrostyrene and saturated aliphatic nitro compounds in tetrahydrofuran are reduced efficiently with stannous iodide and a catalytic amount of concentrated hydrochloric acid to the corresponding 6-ketosteroids, oximes or hydroxylamine derivatives in good yields, respectively.

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