Abstract
The enthalpy and entropy of activation in the homogeneous electrochemical reduction of phosphoric acid esters [(PhO)3–n(BuO)nPO, n = 0–2] are assumed to reflect transition state stabilization of the electron transfer step due to partial bonding between substrate and mediator.
References
1.
Eberson L.
Reactivity and Structure: Concepts in Organic Chemistry,
1987
2.
10.1070/MC1994v004n02ABEH000348_bib2
Budnikova
Zh. Obshch. Khim.,
1992
3.
10.1070/MC1994v004n02ABEH000348_bib3
Kargin
Zh. Obshch. Khim.,
1991
4.
Lexa D., Saveant J.M., Su Khac Binh, Wang D.L.
Journal of the American Chemical Society,
1988
5.
Grimshaw J., Langan J.R., Salmon G.A.
Journal of the Chemical Society Chemical Communications,
1988