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A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle

Galina Dmitrievna Gamalevich 1
Galina Dmitrievna Gamalevich
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
10.1070/MC1994v004n02ABEH000338
Published 1994-04-30
Communication , Volume 4, Issue 2, 40-41
2
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Gamalevich G. D., Serebryakov E. P. A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 40-41.
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Gamalevich G. D., Serebryakov E. P. A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 40-41.
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TY - JOUR
DO - 10.1070/MC1994v004n02ABEH000338
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000338
TI - A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle
T2 - Mendeleev Communications
AU - Gamalevich, Galina Dmitrievna
AU - Serebryakov, Edward Prokof'evich
PY - 1994
DA - 1994/04/30
PB - Mendeleev Communications
SP - 40-41
IS - 2
VL - 4
ER -
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@article{1994_Gamalevich,
author = {Galina Dmitrievna Gamalevich and Edward Prokof'evich Serebryakov},
title = {A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000338},
number = {2},
pages = {40--41},
doi = {10.1070/MC1994v004n02ABEH000338}
}
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Gamalevich, Galina Dmitrievna, and Edward Prokof'evich Serebryakov. “A Chemico-Enzymatic Synthesis of All Four Stereoisomers of 1,6-Dimethyloct-1-yl Formate, an Aggregation Pheromone Mimic for the Smaller Flour Beetle.” Mendeleev Communications, vol. 4, no. 2, Apr. 1994, pp. 40-41. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n02ABEH000338.

Abstract

(2R,6R)-, (2R,6S)-, (2S,6R)- and (2S,6S)-2,6-dimethyloct-1 -yl formates have been prepared from S-(+)- and R-(–)-enantiomers of 3,7-dimethylocta-1,6-diene via enantioselective hydrolysis of (2R/S,6R)- and (2R/S,6S)-2,6-dimethyloct-1-yl formates with porcine pancreatic lipase as the key step.

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