Home / Publications / Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4

Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4

Elisei Sergeevich Rudakov 1
Elisei Sergeevich Rudakov
, 
Alexander I Lutsyk 1
Alexander I Lutsyk
, 
Gennadii Georgievich Gundilovich 1
Gennadii Georgievich Gundilovich
1 L.M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine
10.1070/MC1994v004n01ABEH000336
Published 1994-02-28
Communication , Volume 4, Issue 1, 27-28
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Rudakov E. S., Lutsyk A. I., Gundilovich G. G. Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4 // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 27-28.
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Rudakov E. S., Lutsyk A. I., Gundilovich G. G. Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4 // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 27-28.
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TY - JOUR
DO - 10.1070/MC1994v004n01ABEH000336
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000336
TI - Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4
T2 - Mendeleev Communications
AU - Rudakov, Elisei Sergeevich
AU - Lutsyk, Alexander I
AU - Gundilovich, Gennadii Georgievich
PY - 1994
DA - 1994/02/28
PB - Mendeleev Communications
SP - 27-28
IS - 1
VL - 4
ER -
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@article{1994_Rudakov,
author = {Elisei Sergeevich Rudakov and Alexander I Lutsyk and Gennadii Georgievich Gundilovich},
title = {Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000336},
number = {1},
pages = {27--28},
doi = {10.1070/MC1994v004n01ABEH000336}
}
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Rudakov, Elisei Sergeevich, et al. “Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4.” Mendeleev Communications, vol. 4, no. 1, Feb. 1994, pp. 27-28. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000336.

Abstract

Unexpectedly high differences in propane solubility in the systems HNO3–H2O (salting-in), H3PO4–H2O (salting-out) and H2SO4–H2O (salting-out at low H2SO4 concentrations and salting-in at high concentrations) have been revealed, and the data quantitatively interpreted within the framework of the previously suggested equation relating the excess amounts of solubility with the molar volume of a system; the general nature of these equations for systems of this type has been demonstrated.

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