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The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide

Pavel Stanislavovich Mozhaev 1
Pavel Stanislavovich Mozhaev
,  , 
Galina Anatol'evna Kichigina 1
Galina Anatol'evna Kichigina
, 
Igor Mstislavovich Barkalov 1
Igor Mstislavovich Barkalov
10.1070/MC1994v004n01ABEH000330
Published 1994-02-28
Communication , Volume 4, Issue 1, 17-19
7
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Mozhaev P. S. et al. The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 17-19.
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Mozhaev P. S., Kiryukhin D. P., Kichigina G. A., Barkalov I. M. The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 17-19.
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TY - JOUR
DO - 10.1070/MC1994v004n01ABEH000330
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000330
TI - The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide
T2 - Mendeleev Communications
AU - Mozhaev, Pavel Stanislavovich
AU - Kiryukhin, Dmitrii Pavlovich
AU - Kichigina, Galina Anatol'evna
AU - Barkalov, Igor Mstislavovich
PY - 1994
DA - 1994/02/28
PB - Mendeleev Communications
SP - 17-19
IS - 1
VL - 4
ER -
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@article{1994_Mozhaev,
author = {Pavel Stanislavovich Mozhaev and Dmitrii Pavlovich Kiryukhin and Galina Anatol'evna Kichigina and Igor Mstislavovich Barkalov},
title = {The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000330},
number = {1},
pages = {17--19},
doi = {10.1070/MC1994v004n01ABEH000330}
}
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Mozhaev, Pavel Stanislavovich, et al. “The Formation of Molecular Compounds following Radiolysis of Solid Hydrogen Cyanide.” Mendeleev Communications, vol. 4, no. 1, Feb. 1994, pp. 17-19. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000330.

Abstract

Low-temperature HCN radiolysis (conditions close to those in cosmic space) leads to formation of different molecular compounds; conjugated polymers [C=N–C=N]n, with conjugated chain growth, are formed (colour change orange → brown → black). The polymer gives a singlet EPR signal typical of polyconjugated systems, and crystals of 1,2-diaminomalonodinitrile are also formed. Electrical breakdowns and glow are observed on freezing the HCN; this Is connected with a brittle fracture of HCN crystals leading to electrical charge separation. The freezing out of HCN onto grains of interstellar dust under cosmic conditions would lead to effective coagulation of the dissipated substance at the expense of electrostatic attraction.

References

1.
10.1070/MC1994v004n01ABEH000330_bib1
Calvin
Chemical Evolution, 1969
2.
Cyanoacetylene in Prebiotic Synthesis
Sanchez R.A., Ferris J.P., Orgel L.E.
Science, 1966
4.
HCN: A plausible source of purines, pyrimidines and amino acids on the primitive earth
Ferris J.P., Joshi P.C., Edelson E.H., Lawless J.G.
Journal of Molecular Evolution, 1978
7.
10.1070/MC1994v004n01ABEH000330_bib7
Meisse
Bull. Am. Astronom. Soc., 1991
8.
10.1070/MC1994v004n01ABEH000330_bib8
Sagan
Bull. Am. Astronom. Soc., 1991
11.
Elektrolysen von Cyaniden. I. Elektrolysen Von Cyaniden in w��rigen L�sungen
Schmidt H., Meinert H.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1957
13.
10.1070/MC1994v004n01ABEH000330_bib13
Rappoport
Labortornye metody polucheniya chistykh gazov, 1963
14.
10.1070/MC1994v004n01ABEH000330_bib14
Barkalov
Khim. Vys. Energ., 1990
15.
10.1070/MC1994v004n01ABEH000330_bib15
Physics, Chemistry of the Organic Solid, State, 1965
17.
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds
Stull D.R.
Industrial & Engineering Chemistry, 1947
18.
A quantum chemical study on the mechanism of HCN oligomerization
Guo Hong S., Qu X., Yuan Fu X.
Journal of Molecular Structure THEOCHEM, 1992
19.
10.1070/MC1994v004n01ABEH000330_bib19
Cochran
5th Intl. Symp. on Free Radicals, 1961
20.
ESR Detection of the Cyanogen and Methylene Imino Free Radicals
Cochran E.L., Adrian F.J., Bowers V.A.
Journal of Chemical Physics, 1962
21.
HYDROGEN CYANIDE DIMER AND CHEMICAL EVOLUTION
Kliss R.M., Matthews C.N.
Proceedings of the National Academy of Sciences of the United States of America, 1962
22.
Hydrogen cyanide dimer. Aminocyanocarbene
Moser R.E., Fritsch J.M., Westman T.L., Kliss R.M., Matthews C.N.
Journal of the American Chemical Society, 1967