Abstract
Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.
References
1.
Evans W.J.
Advances in Organometallic Chemistry,
1985
2.
Schumann H., Genthe W.
Handbook on the Physics and Chemistry of Rare Earths,
1984
3.
10.1070/MC1994v004n01ABEH000323_bib3
Organometallic Compounds of the Lanthanides, Actinides and Early Transition Metals,
1985
4.
Xu G.X., Ren J., Huang C.H., Wu J.G.
Pure and Applied Chemistry,
1988
5.
10.1070/MC1994v004n01ABEH000323_bib5
Zagorsky
Mol. Cryst. Liq. Cryst.,
1990
6.
Imamura H., Kitajima K., Tsuchiya S.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases,
1989
7.
10.1070/MC1994v004n01ABEH000323_bib7
Klabunde
Chemistry of Free Atoms and Particles,
1980
8.
W. E. Klotzbücher, Ph. D. Thesis, University of Toronto, 1979.
9.
Klotzbucher W.E.
Cryogenics,
1983
10.
Klotzbücher W.E.
Journal of Molecular Structure,
1988
11.
Klotzbuecher W.E., Ozin G.A.
Inorganic Chemistry,
1980
12.
Jakob M., Micklitz H., Luchner K.
Berichte der Bunsengesellschaft für physikalische Chemie,
1978
13.
Carstens D.H., Brashear W., Eslinger D.R., Gruen D.M.
Applied Spectroscopy,
1972
14.
Beletskaya I.P., Suleimanov G.Z., Shifrina R.R., Mekhdiev R.Y., Agdamskii T.A., Khandozhko V.N., Kolobova N.E.
Journal of Organometallic Chemistry,
1986
15.
Ozin G.A., Klotzbuecher W.E.
Inorganic Chemistry,
1979
16.
Klotzbuecher W.E., Ozin G.A.
Journal of the American Chemical Society,
1978