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A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters

Ton T Zung 1
Ton T Zung
, 
Lev Grigor'evich Bruk 1
Lev Grigor'evich Bruk
, 
Oleg Naumovich Temkin 1
Oleg Naumovich Temkin
10.1070/MC1994v004n01ABEH000321
Published 1994-02-28
Communication , Volume 4, Issue 1, 2-3
15
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Zung T. T., Bruk L. G., Temkin O. N. A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 2-3.
GOST all authors (up to 50) Copy
Zung T. T., Bruk L. G., Temkin O. N. A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 2-3.
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TY - JOUR
DO - 10.1070/MC1994v004n01ABEH000321
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000321
TI - A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters
T2 - Mendeleev Communications
AU - Zung, Ton T
AU - Bruk, Lev Grigor'evich
AU - Temkin, Oleg Naumovich
PY - 1994
DA - 1994/02/28
PB - Mendeleev Communications
SP - 2-3
IS - 1
VL - 4
ER -
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@article{1994_Zung,
author = {Ton T Zung and Lev Grigor'evich Bruk and Oleg Naumovich Temkin},
title = {A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000321},
number = {1},
pages = {2--3},
doi = {10.1070/MC1994v004n01ABEH000321}
}
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Zung, Ton T., et al. “A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters.” Mendeleev Communications, vol. 4, no. 1, Feb. 1994, pp. 2-3. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000321.

Abstract

A new catalytic reaction – oxidative carbonylation of alkynes in the PdCl2–CuCi system – and the reaction mechanism have been proposed based on the unusual effects of oxygen and copper(i) salts on this process and the key role of σ-alkynylcopper(i) complexes in the reaction.

References

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