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Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters

Peter I Pasichnyk 1
Peter I Pasichnyk
, 
Mykhailo K Starchevsky 1
Mykhailo K Starchevsky
, 
Yuriy Antonovich Pazdersky 1
Yuriy Antonovich Pazdersky
, 
Viktor Petrovich Zagorodnikov 2
Viktor Petrovich Zagorodnikov
, 
Michael Natanovich Vargaftik 3
Michael Natanovich Vargaftik
, 
Ilya Iosifovich Moiseev 3
Ilya Iosifovich Moiseev
10.1070/MC1994v004n01ABEH000320
Published 1994-02-28
Communication , Volume 4, Issue 1, 1-2
13
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Pasichnyk P. I. et al. Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 1-2.
GOST all authors (up to 50) Copy
Pasichnyk P. I., Starchevsky M. K., Pazdersky Y. A., Zagorodnikov V. P., Vargaftik M. N., Moiseev I. I. Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 1-2.
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TY - JOUR
DO - 10.1070/MC1994v004n01ABEH000320
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000320
TI - Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters
T2 - Mendeleev Communications
AU - Pasichnyk, Peter I
AU - Starchevsky, Mykhailo K
AU - Pazdersky, Yuriy Antonovich
AU - Zagorodnikov, Viktor Petrovich
AU - Vargaftik, Michael Natanovich
AU - Moiseev, Ilya Iosifovich
PY - 1994
DA - 1994/02/28
PB - Mendeleev Communications
SP - 1-2
IS - 1
VL - 4
ER -
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@article{1994_Pasichnyk,
author = {Peter I Pasichnyk and Mykhailo K Starchevsky and Yuriy Antonovich Pazdersky and Viktor Petrovich Zagorodnikov and Michael Natanovich Vargaftik and Ilya Iosifovich Moiseev},
title = {Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000320},
number = {1},
pages = {1--2},
doi = {10.1070/MC1994v004n01ABEH000320}
}
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Pasichnyk, Peter I., et al. “Oxidation of Propylene to Acrylic Acid and its Esters Catalysed by Palladium Giant Clusters.” Mendeleev Communications, vol. 4, no. 1, Feb. 1994, pp. 1-2. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000320.

Abstract

Propylene has been catalytically oxidized by dioxygen to acrylic acid and/or its esters in high yield (60–80%) in acidified aqueous and/or alcoholic solutions of palladium–561 giant clusters, whereas ethylene has been converted to acetic acid; this is the first example of acid–promoted palladium catalysis of alkene oxidation.

References

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10.1070/MC1994v004n01ABEH000320_bib1
Moiseev
Perspectives in Catalysis, 1992
2.
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Dokl. Akad. Nauk SSSR, 1960
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10.1070/MC1994v004n01ABEH000320_bib3
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Kinet. Katal., 1981
4.
Japan Pat. 26764,1972.
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10.1070/MC1994v004n01ABEH000320_bib5
Fujimoto
J. Japan Petrol. Inst., 1974
6.
Giant palladium clusters as catalysts of oxidative reactions of olefins and alcohols
Vargaftik M.N., Zagorodnikov V.P., Stolarov I.P., Moiseev I.I., Kochubey D.I., Likholobov V.A., Chuvilin A.L., Zamaraev K.I.
Journal of Molecular Catalysis, 1989
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10.1070/MC1994v004n01ABEH000320_bib7
Zagorodnikov
Kinet. Katal., 1986
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10.1070/MC1994v004n01ABEH000320_bib8
Stolarov
Kinet. Katal., 1987