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Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling

Electron Aleksandrovich Mistryukov 1
Electron Aleksandrovich Mistryukov
10.1070/MC1993v003n06ABEH000316
Published 1993-12-31
Communication , Volume 3, Issue 6, 251-251
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Mistryukov E. A. Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 251-251.
GOST all authors (up to 50) Copy
Mistryukov E. A. Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 251-251.
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TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000316
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000316
TI - Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling
T2 - Mendeleev Communications
AU - Mistryukov, Electron Aleksandrovich
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 251-251
IS - 6
VL - 3
ER -
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@article{1993_Mistryukov,
author = {Electron Aleksandrovich Mistryukov},
title = {Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000316},
number = {6},
pages = {251--251},
doi = {10.1070/MC1993v003n06ABEH000316}
}
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Mistryukov, Electron Aleksandrovich. “Ultrasound in Organic Synthesis. Electron-transfer Catalysis in Li-TMSCI Reductive Benzene Silylation and TMSCI Wurtz Coupling.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 251-251. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000316.

Abstract

Di-tert-butylbiphenyl 1 and hexamethylphosphoric triamide (HMPT) are efficient catalysts for reductive benzene silylation or hexamethyldisilane 3 formation, respectively.

References

1.
Alkyllithium reagents from alkyl halides and lithium radical anions
Freeman P.K., Hutchinson L.L.
Journal of Organic Chemistry, 1980
2.
The Synthesis of 3,6-Disilyl-1,4-Cyclohexadienes by the Trapping of Benzene Anion-Radicals
Weyenberg D.R., Toporcer L.H.
Journal of the American Chemical Society, 1962