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Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates

Michael Natanovich Vargaftik 1
Michael Natanovich Vargaftik
, 
Yuri Timofeevich Struchkov 2
Yuri Timofeevich Struchkov
, 
Aleksandr Il'ich Yanovsky 2
Aleksandr Il'ich Yanovsky
, 
Peter M Maitlis 3
Peter M Maitlis
10.1070/MC1993v003n06ABEH000314
Published 1993-12-31
Communication , Volume 3, Issue 6, 247-249
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Vargaftik M. N. et al. Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 247-249.
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Vargaftik M. N., Struchkov Y. T., Yanovsky A. I., Maitlis P. M. Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 247-249.
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TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000314
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000314
TI - Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates
T2 - Mendeleev Communications
AU - Vargaftik, Michael Natanovich
AU - Struchkov, Yuri Timofeevich
AU - Yanovsky, Aleksandr Il'ich
AU - Maitlis, Peter M
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 247-249
IS - 6
VL - 3
ER -
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@article{1993_Vargaftik,
author = {Michael Natanovich Vargaftik and Yuri Timofeevich Struchkov and Aleksandr Il'ich Yanovsky and Peter M Maitlis},
title = {Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000314},
number = {6},
pages = {247--249},
doi = {10.1070/MC1993v003n06ABEH000314}
}
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Vargaftik, Michael Natanovich, et al. “Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 247-249. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000314.

Abstract

Reaction of [{Cp*RhCI2}2] (Cp*=η5-C5Me5) with the PPN (PPN+ = Ph3P=N=PPh3+) salts of iso- and heteropolymolybdates offers a good route to polyoxometallates containing organometallics; the syntheses and X-ray structures of [(Cp*Rh)4(Mo4O16)], containing a tris-cubane oxotetramolybdenum skeleton (derived from (PPN)2[MoO4]-6H2O) and the ionic [Cp*RhCl3RhCp*]+[PPN]+2[PMo12O40]3− (derived from (PPN)2[Mo2O7]) are described.

References

1.
Molecular Organometallic Chemistry on Surfaces: Reactivity of Metal Carbonyls on Metal Oxides
Lamb H.H., Gates B.C., Knözinger H.
Angewandte Chemie International Edition in English, 1988
2.
Cubane-type clusters as potential models for inorganic solid surfaces
Isobe K., Yagasaki A.
Accounts of Chemical Research, 1993
3.
Martinsen A., Songstad J., Larsson R., Pouchard M., Hagenmuller P., Andresen A.F.
Acta Chemica Scandinavica, 1977
5.
10.1070/MC1993v003n06ABEH000314_bib4
Andrianov
Koord. Khim., 1986
8.
Synthesis and structure of the {[(C7H8)Rh]5(cis-Nb2W4O19)2}3- anion
Besecker C.J., Klemperer W.G., Day V.W.
Journal of the American Chemical Society, 1982
11.
Solid-state chemistry of molecular metal oxide clusters. Bis(triphenylphosphine)rhodium(I) carbonyl derivatives
Siedle A.R., Gleason W.B., Newmark R.A., Skarjune R.P., Lyon P.A., Markell C.G., Hodgson K.O., Roe A.L.
Inorganic Chemistry, 1990
12.
Bifunctional rhodium-oxometalate catalysts
Siedle A.R., Markell C.G., Lyon P.A., Hodgson K.O., Roe A.L.
Inorganic Chemistry, 1987
13.
Solid-state organometallic chemistry of molecular metal oxide clusters: C―H activation by an iridium polyoxometalate
Siedle A.R., Newmark R.A., Brown-Wensley K.A., Skarjune R.P., Haddad L.C., Hodgson K.O., Roe A.L.
Organometallics, 1988