Home / Publications / A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes

A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes

Viacheslav A Petrov 1
Viacheslav A Petrov
, 
Todd E Mlsna 1
Todd E Mlsna
, 
Darryl D DesMarteau 1
Darryl D DesMarteau
10.1070/MC1993v003n06ABEH000309
Published 1993-12-31
Communication , Volume 3, Issue 6, 240-240
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Petrov V. A., Mlsna T. E., DesMarteau D. D. A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 240-240.
GOST all authors (up to 50) Copy
Petrov V. A., Mlsna T. E., DesMarteau D. D. A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 240-240.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000309
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000309
TI - A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes
T2 - Mendeleev Communications
AU - Petrov, Viacheslav A
AU - Mlsna, Todd E
AU - DesMarteau, Darryl D
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 240-240
IS - 6
VL - 3
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Petrov,
author = {Viacheslav A Petrov and Todd E Mlsna and Darryl D DesMarteau},
title = {A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000309},
number = {6},
pages = {240--240},
doi = {10.1070/MC1993v003n06ABEH000309}
}
MLA
Cite this
MLA Copy
Petrov, Viacheslav A., et al. “A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 240-240. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000309.

Abstract

Methylfluorovinylsilanes and stannanes Me4–xM(CF=CF2)x(M = Sn, x= 1; Si, x= 1,2) can be prepared in good to excellent yields by the reaction of CF2=CFBr with a mixture of the corresponding Me4–xMCIx and P(NR2)3 in polar solvent. Similarly, the novel silane CF3 (SiMe3)C=CF2 was obtained from CF3CBr=CF2

References

2.
Fluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds
Kotun S.P., Anderson J.D., Des Marteau D.D.
Journal of Organic Chemistry, 1992
3.
10.1070/MC1993v003n06ABEH000309_bib3
Petrov
Izv. Akad. Nauk SSSR, Ser. Khim., 1989
4.
10.1070/MC1993v003n06ABEH000309_bib4
Starlin
Izv. Akad. Nauk SSSR. Ser. Khim., 1959
6.
Die ersten CF3-substituierten organyl(chlor)silane
Ruppert I., Schlich K., Volbach W.
Tetrahedron Letters, 1984
7.
10.1070/MC1993v003n06ABEH000309_bib7
Marchenko
Zh. Obshch. Khim., 1980
9.
10.1070/MC1993v003n06ABEH000309_bib9
M
Izv. Akad. Nauk SSR, Ser. Khim., 1986
10.
10.1070/MC1993v003n06ABEH000309_bib10
C
J. Chem. Phys., 1966
12.
REACTIONS OF ORGANOTIN COMPOUNDS: VI. THE REACTIONS OF TIN HYDRIDES WITH PERFLUOROVINYL TIN COMPOUNDS
Beveridge A.D., Clark H.C., Kwon J.T.
Canadian Journal of Chemistry, 1966