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Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene

Oleg Grigor'evich Kulinkovich 1
Oleg Grigor'evich Kulinkovich
, 
Andrey I Savchenko 1
Andrey I Savchenko
, 
Sergey V Sviridov 1
Sergey V Sviridov
, 
Dmitry A Vasilevski 1
Dmitry A Vasilevski
10.1070/MC1993v003n06ABEH000304
Published 1993-12-31
Communication , Volume 3, Issue 6, 230-231
67
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Kulinkovich O. G. et al. Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 230-231.
GOST all authors (up to 50) Copy
Kulinkovich O. G., Savchenko A. I., Sviridov S. V., Vasilevski D. A. Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 230-231.
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TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000304
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000304
TI - Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene
T2 - Mendeleev Communications
AU - Kulinkovich, Oleg Grigor'evich
AU - Savchenko, Andrey I
AU - Sviridov, Sergey V
AU - Vasilevski, Dmitry A
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 230-231
IS - 6
VL - 3
ER -
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@article{1993_Kulinkovich,
author = {Oleg Grigor'evich Kulinkovich and Andrey I Savchenko and Sergey V Sviridov and Dmitry A Vasilevski},
title = {Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000304},
number = {6},
pages = {230--231},
doi = {10.1070/MC1993v003n06ABEH000304}
}
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Kulinkovich, Oleg Grigor'evich, et al. “Titanium(IV) Isopropoxide-catalysed Reaction of Ethylmagnesium Bromide with Ethyl Acetate in the Presence of Styrene.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 230-231. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000304.

Abstract

Reaction of ethylmagnesium bromide with ethyl acetate in the presence of styrene and titanium(IV) isopropoxide as a catalyst leads to (Z)-1-methyl-2-phenylcyclopropanol in 42% yield.

References

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10.1070/MC1993v003n06ABEH000304_bib2
Kulinkovich
Zh. Org. Khim., 1991
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A Synthesis of Cyclopropyl Acetates1,2
Freeman J.P.
Journal of Organic Chemistry, 1964