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Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes

Alexander Vasil'evich Usatov 1
Alexander Vasil'evich Usatov
, 
Alexander L'vovich Blumenfeld 1
Alexander L'vovich Blumenfeld
, 
Eugenii Victorovich Vorontsov 1
Eugenii Victorovich Vorontsov
, 
Lyudmila Evgenievna Vinogradova 1
Lyudmila Evgenievna Vinogradova
, 
Yurii Nikolaevich Novikov 1
Yurii Nikolaevich Novikov
10.1070/MC1993v003n06ABEH000303
Published 1993-12-31
Communication , Volume 3, Issue 6, 229-230
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Usatov A. V. et al. Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 229-230.
GOST all authors (up to 50) Copy
Usatov A. V., Blumenfeld A. L., Vorontsov E. V., Vinogradova L. E., Novikov Y. N. Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 229-230.
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TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000303
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000303
TI - Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes
T2 - Mendeleev Communications
AU - Usatov, Alexander Vasil'evich
AU - Blumenfeld, Alexander L'vovich
AU - Vorontsov, Eugenii Victorovich
AU - Vinogradova, Lyudmila Evgenievna
AU - Novikov, Yurii Nikolaevich
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 229-230
IS - 6
VL - 3
ER -
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@article{1993_Usatov,
author = {Alexander Vasil'evich Usatov and Alexander L'vovich Blumenfeld and Eugenii Victorovich Vorontsov and Lyudmila Evgenievna Vinogradova and Yurii Nikolaevich Novikov},
title = {Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000303},
number = {6},
pages = {229--230},
doi = {10.1070/MC1993v003n06ABEH000303}
}
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Usatov, Alexander Vasil'evich, et al. “Organometallic Hydrides as Reactants in Fullerene Chemistry. Synthesis and Configuration of (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) Complexes.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 229-230. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000303.
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Abstract

Rhodium hydride HRh(CO)(PPh3)3 reacts with fullerenes C60 and C70 yielding (η2-Cn)RhH(CO)(PPh3)2 (n = 60,70) complexes whose composition and configuration have been established by means of IR and NMR spectroscopy.

References

1.
Metal complexes of buckminsterfullerene (C60)
Fagan P.J., Calabrese J.C., Malone B.
Accounts of Chemical Research, 1992
2.
Organometallic chemistry with buckminsterfullerene. Preparation and properties of an indenyliridium(I) complex
Koefod R.S., Hudgens M.F., Shapley J.R.
Journal of the American Chemical Society, 1991
4.
(.eta.2-C70)Ir(CO)Cl(PPh3)2: the synthesis and structure of an iridium organometallic derivative of a higher fullerene
Balch A.L., Catalano V.J., Lee J.W., Olmstead M.M., Parkin S.R.
Journal of the American Chemical Society, 1991
5.
Supramolecular aggregation of an (.eta.2-C60) iridium complex involving phenyl chelation of the fullerene
Balch A.L., Catalano V.J., Lee J.W., Olmstead M.M.
Journal of the American Chemical Society, 1992
7.
A double addition product of C60: C60{Ir(CO)Cl(PMe2Ph)2}2. Individual crystallization of two conformational isomers
Balch A.L., Lee J.W., Noll B.C., Olmstead M.M.
Journal of the American Chemical Society, 1992
8.
Synthesis, crystal, and molecular structure of the palladium(0)-fullerene derivative (.eta.2-C60)Pd(PPh3)2
Bashilov V.V., Petrovskii P.V., Sokolov V.I., Lindeman S.V., Guzey I.A., Struchkov Y.T.
Organometallics, 1993
9.
10.1070/MC1993v003n06ABEH000303_bib9
Bashilov
Izv. Akad. Nauk, Ser. Khim., 1993
10.
10.1070/MC1993v003n06ABEH000303_bib10
Collman
Principles and Applications of Organotransition Metal Chemistry, 1987
11.
10.1070/MC1993v003n06ABEH000303_bib11
Muetterties
1971
12.
10.1070/MC1993v003n06ABEH000303_bib12
Henrici-Olivé
Coordination and Catalysis, 1977
15.
Hydride complexes of the transition metals
Kaesz H.D., Saillant R.B.
Chemical Reviews, 1972
16.
Further studies on hydridocarbonyltris(triphenylphosphine)rhodium(I); intermediate species in hydroformylation; rhodium and iridium analogues
Yagupsky G., Brown C.K., Wilkinson G.
Journal of the Chemical Society A Inorganic Physical Theoretical, 1970