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Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives

Eugeny Victorovich Gorobets 1
Eugeny Victorovich Gorobets
,  , 
Genrikh Alexandrovich Tolstikov 2
Genrikh Alexandrovich Tolstikov
10.1070/MC1993v003n05ABEH000302
Published 1993-10-30
Communication , Volume 3, Issue 5, 217-219
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Gorobets E. V., Kutchin A. V., Tolstikov G. A. Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 217-219.
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Gorobets E. V., Kutchin A. V., Tolstikov G. A. Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 217-219.
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TY - JOUR
DO - 10.1070/MC1993v003n05ABEH000302
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000302
TI - Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives
T2 - Mendeleev Communications
AU - Gorobets, Eugeny Victorovich
AU - Kutchin, Aleksandr Vasilevich
AU - Tolstikov, Genrikh Alexandrovich
PY - 1993
DA - 1993/10/30
PB - Mendeleev Communications
SP - 217-219
IS - 5
VL - 3
ER -
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@article{1993_Gorobets,
author = {Eugeny Victorovich Gorobets and Aleksandr Vasilevich Kutchin and Genrikh Alexandrovich Tolstikov},
title = {Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000302},
number = {5},
pages = {217--219},
doi = {10.1070/MC1993v003n05ABEH000302}
}
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Gorobets, Eugeny Victorovich, et al. “Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives.” Mendeleev Communications, vol. 3, no. 5, Oct. 1993, pp. 217-219. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000302.

Abstract

(1R,4R,6R)- and (1R,4R,6S)-7-(Methoxymethyl)menth-2-en-6-ol 7 and 8, (1R,4R)-7-(methoxymethyl)menth-2-en-6-one 10, (1 R,4R)-7-(methoxymethyl)menth-2-ene 5 and their saturated analogues have been synthesized from (1 R,4R,6S)-6-(dibromoaluminio)-7-(methoxymethyl)menth-2-ene 3, prepared under hydroaiumination of the methyl ether of 2-{(1 R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl}ethanol with the LiAIH4·3AIBr3 system.

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