Home / Publications / Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core

Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core

Elena Okkasovna Tolkacheva 1
Elena Okkasovna Tolkacheva
, 
Vladimir Semenovich Sergienko 2
Vladimir Semenovich Sergienko
, 
Andrei Borisovich Ilyukhin 2
Andrei Borisovich Ilyukhin
1 State Research Institute of Chemical Reagents and Highly Pure Chemical Substances, Moscow, Russian Federation
10.1070/MC1993v003n05ABEH000294
Published 1993-10-30
Communication , Volume 3, Issue 5, 206-208
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Tolkacheva E. O., Sergienko V. S., Ilyukhin A. B. Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 206-208.
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Tolkacheva E. O., Sergienko V. S., Ilyukhin A. B. Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 206-208.
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TY - JOUR
DO - 10.1070/MC1993v003n05ABEH000294
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000294
TI - Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core
T2 - Mendeleev Communications
AU - Tolkacheva, Elena Okkasovna
AU - Sergienko, Vladimir Semenovich
AU - Ilyukhin, Andrei Borisovich
PY - 1993
DA - 1993/10/30
PB - Mendeleev Communications
SP - 206-208
IS - 5
VL - 3
ER -
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@article{1993_Tolkacheva,
author = {Elena Okkasovna Tolkacheva and Vladimir Semenovich Sergienko and Andrei Borisovich Ilyukhin},
title = {Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000294},
number = {5},
pages = {206--208},
doi = {10.1070/MC1993v003n05ABEH000294}
}
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Tolkacheva, Elena Okkasovna, et al. “Synthesis, IR Study and Crystal Structure of a Novel Mononuclear Tungsten(VI) Oxo Complex with 1-Hydroxyethylidenediphosphonic Acid, Exhibiting a WO3 Core.” Mendeleev Communications, vol. 3, no. 5, Oct. 1993, pp. 206-208. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000294.

Abstract

The synthesis and IR spectroscopic and X-ray diffraction studies of [C(NH2)3]5[WO3(L*)]·4.5H2O, the first WVI monomeric compound to contain a WO3 group, have been carried out and an unusual structure (with ratio M:L* = 1:1) has been observed for both independent complex anions: the tungsten atoms have fac-octahedral coordination with three terminal oxo-atoms (Ot), two O(P) atoms and one O(C) atom of the tridentate ligand L* in the trans position to Ot.

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