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Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones

Zhanna Aleksandrovna Krasnaya 1
Zhanna Aleksandrovna Krasnaya
, 
Ekaterina V Grechkina 1
Ekaterina V Grechkina
, 
Valentin Sergeevich Bogdanov 1
Valentin Sergeevich Bogdanov
10.1070/MC1993v003n05ABEH000285
Published 1993-10-30
Communication , Volume 3, Issue 5, 195-196
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Krasnaya Z. A., Grechkina E. V., Bogdanov V. S. Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 195-196.
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Krasnaya Z. A., Grechkina E. V., Bogdanov V. S. Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 195-196.
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TY - JOUR
DO - 10.1070/MC1993v003n05ABEH000285
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000285
TI - Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones
T2 - Mendeleev Communications
AU - Krasnaya, Zhanna Aleksandrovna
AU - Grechkina, Ekaterina V
AU - Bogdanov, Valentin Sergeevich
PY - 1993
DA - 1993/10/30
PB - Mendeleev Communications
SP - 195-196
IS - 5
VL - 3
ER -
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@article{1993_Krasnaya,
author = {Zhanna Aleksandrovna Krasnaya and Ekaterina V Grechkina and Valentin Sergeevich Bogdanov},
title = {Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000285},
number = {5},
pages = {195--196},
doi = {10.1070/MC1993v003n05ABEH000285}
}
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Krasnaya, Zhanna Aleksandrovna, et al. “Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones.” Mendeleev Communications, vol. 3, no. 5, Oct. 1993, pp. 195-196. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000285.

Abstract

Condensation of α,β-unsaturated β-dimethylaminoaldehydes with heptane-2,4,6-trione unexpectedly affords a new type of substituted phenols (4a–c; 5a,c) due to intramolecular cyclization accompanied by 1,6-deamination.

References

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